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cis-Diaquabis[dimethyl (phenylsulfonylimino)phosphonato]cobalt(II)
In the title diaquacobalt complex, [Co(C(8)H(11)NO(5)PS)(2)(H(2)O)(2)], the Co(II) atom is surrounded by six O atoms belonging to the phosphoryl and sulfonyl groups of two deprotonated chelate ligands and two additional O atoms from water molecules which are in cis positions with respect to one an...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051992/ https://www.ncbi.nlm.nih.gov/pubmed/21522293 http://dx.doi.org/10.1107/S1600536811006027 |
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author | Trush, Elizaveta A. Trush, Victor A. Sliva, Tetyana Yu. Konovalova, Irina S. Amirkhanov, Volodymyr M. |
author_facet | Trush, Elizaveta A. Trush, Victor A. Sliva, Tetyana Yu. Konovalova, Irina S. Amirkhanov, Volodymyr M. |
author_sort | Trush, Elizaveta A. |
collection | PubMed |
description | In the title diaquacobalt complex, [Co(C(8)H(11)NO(5)PS)(2)(H(2)O)(2)], the Co(II) atom is surrounded by six O atoms belonging to the phosphoryl and sulfonyl groups of two deprotonated chelate ligands and two additional O atoms from water molecules which are in cis positions with respect to one another. The coordination environment of cobalt can be described as a distorted octahedron. O—H⋯O hydrogen bonds between the water and sulfonyl O atoms of neighboring molecules form chains running parallel to [010]. Two methoxy groups attached to one phosphorus are disordered over two sets of sites in a 0.6:0.4 ratio. |
format | Text |
id | pubmed-3051992 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30519922011-04-26 cis-Diaquabis[dimethyl (phenylsulfonylimino)phosphonato]cobalt(II) Trush, Elizaveta A. Trush, Victor A. Sliva, Tetyana Yu. Konovalova, Irina S. Amirkhanov, Volodymyr M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title diaquacobalt complex, [Co(C(8)H(11)NO(5)PS)(2)(H(2)O)(2)], the Co(II) atom is surrounded by six O atoms belonging to the phosphoryl and sulfonyl groups of two deprotonated chelate ligands and two additional O atoms from water molecules which are in cis positions with respect to one another. The coordination environment of cobalt can be described as a distorted octahedron. O—H⋯O hydrogen bonds between the water and sulfonyl O atoms of neighboring molecules form chains running parallel to [010]. Two methoxy groups attached to one phosphorus are disordered over two sets of sites in a 0.6:0.4 ratio. International Union of Crystallography 2011-02-23 /pmc/articles/PMC3051992/ /pubmed/21522293 http://dx.doi.org/10.1107/S1600536811006027 Text en © Trush et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Trush, Elizaveta A. Trush, Victor A. Sliva, Tetyana Yu. Konovalova, Irina S. Amirkhanov, Volodymyr M. cis-Diaquabis[dimethyl (phenylsulfonylimino)phosphonato]cobalt(II) |
title |
cis-Diaquabis[dimethyl (phenylsulfonylimino)phosphonato]cobalt(II) |
title_full |
cis-Diaquabis[dimethyl (phenylsulfonylimino)phosphonato]cobalt(II) |
title_fullStr |
cis-Diaquabis[dimethyl (phenylsulfonylimino)phosphonato]cobalt(II) |
title_full_unstemmed |
cis-Diaquabis[dimethyl (phenylsulfonylimino)phosphonato]cobalt(II) |
title_short |
cis-Diaquabis[dimethyl (phenylsulfonylimino)phosphonato]cobalt(II) |
title_sort | cis-diaquabis[dimethyl (phenylsulfonylimino)phosphonato]cobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051992/ https://www.ncbi.nlm.nih.gov/pubmed/21522293 http://dx.doi.org/10.1107/S1600536811006027 |
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