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cis-Diaqua­bis­[dimethyl (phenyl­sulfonyl­imino)­phospho­nato]cobalt(II)

In the title diaqua­cobalt complex, [Co(C(8)H(11)NO(5)PS)(2)(H(2)O)(2)], the Co(II) atom is surrounded by six O atoms belonging to the phosphoryl and sulfonyl groups of two deprotonated chelate ligands and two additional O atoms from water mol­ecules which are in cis positions with respect to one an...

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Autores principales: Trush, Elizaveta A., Trush, Victor A., Sliva, Tetyana Yu., Konovalova, Irina S., Amirkhanov, Volodymyr M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051992/
https://www.ncbi.nlm.nih.gov/pubmed/21522293
http://dx.doi.org/10.1107/S1600536811006027
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author Trush, Elizaveta A.
Trush, Victor A.
Sliva, Tetyana Yu.
Konovalova, Irina S.
Amirkhanov, Volodymyr M.
author_facet Trush, Elizaveta A.
Trush, Victor A.
Sliva, Tetyana Yu.
Konovalova, Irina S.
Amirkhanov, Volodymyr M.
author_sort Trush, Elizaveta A.
collection PubMed
description In the title diaqua­cobalt complex, [Co(C(8)H(11)NO(5)PS)(2)(H(2)O)(2)], the Co(II) atom is surrounded by six O atoms belonging to the phosphoryl and sulfonyl groups of two deprotonated chelate ligands and two additional O atoms from water mol­ecules which are in cis positions with respect to one another. The coordination environment of cobalt can be described as a distorted octa­hedron. O—H⋯O hydrogen bonds between the water and sulfonyl O atoms of neighboring mol­ecules form chains running parallel to [010]. Two methoxy groups attached to one phosphorus are disordered over two sets of sites in a 0.6:0.4 ratio.
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spelling pubmed-30519922011-04-26 cis-Diaqua­bis­[dimethyl (phenyl­sulfonyl­imino)­phospho­nato]cobalt(II) Trush, Elizaveta A. Trush, Victor A. Sliva, Tetyana Yu. Konovalova, Irina S. Amirkhanov, Volodymyr M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title diaqua­cobalt complex, [Co(C(8)H(11)NO(5)PS)(2)(H(2)O)(2)], the Co(II) atom is surrounded by six O atoms belonging to the phosphoryl and sulfonyl groups of two deprotonated chelate ligands and two additional O atoms from water mol­ecules which are in cis positions with respect to one another. The coordination environment of cobalt can be described as a distorted octa­hedron. O—H⋯O hydrogen bonds between the water and sulfonyl O atoms of neighboring mol­ecules form chains running parallel to [010]. Two methoxy groups attached to one phosphorus are disordered over two sets of sites in a 0.6:0.4 ratio. International Union of Crystallography 2011-02-23 /pmc/articles/PMC3051992/ /pubmed/21522293 http://dx.doi.org/10.1107/S1600536811006027 Text en © Trush et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Trush, Elizaveta A.
Trush, Victor A.
Sliva, Tetyana Yu.
Konovalova, Irina S.
Amirkhanov, Volodymyr M.
cis-Diaqua­bis­[dimethyl (phenyl­sulfonyl­imino)­phospho­nato]cobalt(II)
title cis-Diaqua­bis­[dimethyl (phenyl­sulfonyl­imino)­phospho­nato]cobalt(II)
title_full cis-Diaqua­bis­[dimethyl (phenyl­sulfonyl­imino)­phospho­nato]cobalt(II)
title_fullStr cis-Diaqua­bis­[dimethyl (phenyl­sulfonyl­imino)­phospho­nato]cobalt(II)
title_full_unstemmed cis-Diaqua­bis­[dimethyl (phenyl­sulfonyl­imino)­phospho­nato]cobalt(II)
title_short cis-Diaqua­bis­[dimethyl (phenyl­sulfonyl­imino)­phospho­nato]cobalt(II)
title_sort cis-diaqua­bis­[dimethyl (phenyl­sulfonyl­imino)­phospho­nato]cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051992/
https://www.ncbi.nlm.nih.gov/pubmed/21522293
http://dx.doi.org/10.1107/S1600536811006027
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