Bis(4-ethyl­benzoato-κO)bis­(nicotin­amide-κN (1))zinc(II)

The title Zn(II) complex, [Zn(C(9)H(9)O(2))(2)(C(6)H(6)N(2)O)(2)], contains two 4-ethyl­benzoate and two nicotinamide monodentate ligands, leading to a distorted tetrahedral coordination of the Zn(II) ion. The dihedral angles between the carboxyl­ate groups and the adjacent benzene rings are 10.33 (...

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Autores principales: Necefoğlu, Hacali, Özbek, Füreya Elif, Aktaş, Vedat, Tercan, Barış, Hökelek, Tuncer
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051993/
https://www.ncbi.nlm.nih.gov/pubmed/21522302
http://dx.doi.org/10.1107/S1600536811006830
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author Necefoğlu, Hacali
Özbek, Füreya Elif
Aktaş, Vedat
Tercan, Barış
Hökelek, Tuncer
author_facet Necefoğlu, Hacali
Özbek, Füreya Elif
Aktaş, Vedat
Tercan, Barış
Hökelek, Tuncer
author_sort Necefoğlu, Hacali
collection PubMed
description The title Zn(II) complex, [Zn(C(9)H(9)O(2))(2)(C(6)H(6)N(2)O)(2)], contains two 4-ethyl­benzoate and two nicotinamide monodentate ligands, leading to a distorted tetrahedral coordination of the Zn(II) ion. The dihedral angles between the carboxyl­ate groups and the adjacent benzene rings are 10.33 (13) and 2.38 (11)°, while opposite pyridine and benzene rings are oriented at dihedral angles of 68.46 (5) and 81.09 (6)°. In the crystal, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules, forming a three-dimensional network. C—H⋯O inter­actions also occur as well as two weak C—H⋯π inter­actions involving the benzene rings.
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spelling pubmed-30519932011-04-26 Bis(4-ethyl­benzoato-κO)bis­(nicotin­amide-κN (1))zinc(II) Necefoğlu, Hacali Özbek, Füreya Elif Aktaş, Vedat Tercan, Barış Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title Zn(II) complex, [Zn(C(9)H(9)O(2))(2)(C(6)H(6)N(2)O)(2)], contains two 4-ethyl­benzoate and two nicotinamide monodentate ligands, leading to a distorted tetrahedral coordination of the Zn(II) ion. The dihedral angles between the carboxyl­ate groups and the adjacent benzene rings are 10.33 (13) and 2.38 (11)°, while opposite pyridine and benzene rings are oriented at dihedral angles of 68.46 (5) and 81.09 (6)°. In the crystal, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules, forming a three-dimensional network. C—H⋯O inter­actions also occur as well as two weak C—H⋯π inter­actions involving the benzene rings. International Union of Crystallography 2011-02-26 /pmc/articles/PMC3051993/ /pubmed/21522302 http://dx.doi.org/10.1107/S1600536811006830 Text en © Necefoğlu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Necefoğlu, Hacali
Özbek, Füreya Elif
Aktaş, Vedat
Tercan, Barış
Hökelek, Tuncer
Bis(4-ethyl­benzoato-κO)bis­(nicotin­amide-κN (1))zinc(II)
title Bis(4-ethyl­benzoato-κO)bis­(nicotin­amide-κN (1))zinc(II)
title_full Bis(4-ethyl­benzoato-κO)bis­(nicotin­amide-κN (1))zinc(II)
title_fullStr Bis(4-ethyl­benzoato-κO)bis­(nicotin­amide-κN (1))zinc(II)
title_full_unstemmed Bis(4-ethyl­benzoato-κO)bis­(nicotin­amide-κN (1))zinc(II)
title_short Bis(4-ethyl­benzoato-κO)bis­(nicotin­amide-κN (1))zinc(II)
title_sort bis(4-ethyl­benzoato-κo)bis­(nicotin­amide-κn (1))zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051993/
https://www.ncbi.nlm.nih.gov/pubmed/21522302
http://dx.doi.org/10.1107/S1600536811006830
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AT ozbekfureyaelif bis4ethylbenzoatokobisnicotinamidekn1zincii
AT aktasvedat bis4ethylbenzoatokobisnicotinamidekn1zincii
AT tercanbarıs bis4ethylbenzoatokobisnicotinamidekn1zincii
AT hokelektuncer bis4ethylbenzoatokobisnicotinamidekn1zincii

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