{6,6′-Dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolato}nickel(II) dimethyl­formamide monosolvate

In the title compound, [Ni(C(18)H(18)N(2)O(4))]·C(3)H(7)NO, the central Ni(II) atom is in a square-planar O(2)N(2) coordination environment. The planar Ni–salen moieties (r.m.s. deviation for the plane through the conjugated part of the Ni–salen group = 0.07 Å) form parallel stacks in the a-axis dir...

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Detalles Bibliográficos
Autores principales: Ayikoé, Kouassi, Butcher, Ray J., Gultneh, Yilma
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051997/
https://www.ncbi.nlm.nih.gov/pubmed/21522259
http://dx.doi.org/10.1107/S1600536811004818
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author Ayikoé, Kouassi
Butcher, Ray J.
Gultneh, Yilma
author_facet Ayikoé, Kouassi
Butcher, Ray J.
Gultneh, Yilma
author_sort Ayikoé, Kouassi
collection PubMed
description In the title compound, [Ni(C(18)H(18)N(2)O(4))]·C(3)H(7)NO, the central Ni(II) atom is in a square-planar O(2)N(2) coordination environment. The planar Ni–salen moieties (r.m.s. deviation for the plane through the conjugated part of the Ni–salen group = 0.07 Å) form parallel stacks in the a-axis direction, with alternating Ni⋯Ni separations of 3.5339 (7) and 3.6165 (7) Å. In the crystal, there are weak inter­molecular C—H⋯O inter­actions involving the dimethyl­formamide O and phenolate O atoms.
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spelling pubmed-30519972011-04-26 {6,6′-Dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolato}nickel(II) dimethyl­formamide monosolvate Ayikoé, Kouassi Butcher, Ray J. Gultneh, Yilma Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(18)H(18)N(2)O(4))]·C(3)H(7)NO, the central Ni(II) atom is in a square-planar O(2)N(2) coordination environment. The planar Ni–salen moieties (r.m.s. deviation for the plane through the conjugated part of the Ni–salen group = 0.07 Å) form parallel stacks in the a-axis direction, with alternating Ni⋯Ni separations of 3.5339 (7) and 3.6165 (7) Å. In the crystal, there are weak inter­molecular C—H⋯O inter­actions involving the dimethyl­formamide O and phenolate O atoms. International Union of Crystallography 2011-02-12 /pmc/articles/PMC3051997/ /pubmed/21522259 http://dx.doi.org/10.1107/S1600536811004818 Text en © Ayikoé et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ayikoé, Kouassi
Butcher, Ray J.
Gultneh, Yilma
{6,6′-Dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolato}nickel(II) dimethyl­formamide monosolvate
title {6,6′-Dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolato}nickel(II) dimethyl­formamide monosolvate
title_full {6,6′-Dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolato}nickel(II) dimethyl­formamide monosolvate
title_fullStr {6,6′-Dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolato}nickel(II) dimethyl­formamide monosolvate
title_full_unstemmed {6,6′-Dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolato}nickel(II) dimethyl­formamide monosolvate
title_short {6,6′-Dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolato}nickel(II) dimethyl­formamide monosolvate
title_sort {6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolato}nickel(ii) dimethyl­formamide monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051997/
https://www.ncbi.nlm.nih.gov/pubmed/21522259
http://dx.doi.org/10.1107/S1600536811004818
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AT butcherrayj 66dimethoxy22ethane12diylbisnitrilomethanylylidenediphenolatonickeliidimethylformamidemonosolvate
AT gultnehyilma 66dimethoxy22ethane12diylbisnitrilomethanylylidenediphenolatonickeliidimethylformamidemonosolvate

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