{μ-6,6′-Dimeth­oxy-2,2-[propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}trinitratocopper(II)dysprosium(III) methanol monosolvate

In the title heterodinuclear salen-type complex, [CuDy(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)OH, the copper(II) ion is tetra­coordinated by two imino N atoms [Cu—N = 1.961 (4) and 1.968 (4) Å] and two phenolate O atoms [Cu—O = 1.931 (3) and 1.938 (3) Å] in a planar geometry. The ten-coordin­ate Dy(III...

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Detalles Bibliográficos
Autores principales: Xu, Lili, Li, Hong-Feng, Chen, Peng, Yan, Peng-Fei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051998/
https://www.ncbi.nlm.nih.gov/pubmed/21522291
http://dx.doi.org/10.1107/S1600536811005253
Descripción
Sumario:In the title heterodinuclear salen-type complex, [CuDy(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)OH, the copper(II) ion is tetra­coordinated by two imino N atoms [Cu—N = 1.961 (4) and 1.968 (4) Å] and two phenolate O atoms [Cu—O = 1.931 (3) and 1.938 (3) Å] in a planar geometry. The ten-coordin­ate Dy(III) ion is ligated by six O atoms of three nitrate groups and four O atoms from the ligand [Dy—O = 2.368 (3)–2.601 (3) Å]. In the crystal, complex mol­ecules and solvent mol­ecules are linked by inter­molecular O—H⋯O hydrogen bonds.

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