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{μ-6,6′-Dimethoxy-2,2-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}trinitratocopper(II)dysprosium(III) methanol monosolvate
In the title heterodinuclear salen-type complex, [CuDy(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)OH, the copper(II) ion is tetracoordinated by two imino N atoms [Cu—N = 1.961 (4) and 1.968 (4) Å] and two phenolate O atoms [Cu—O = 1.931 (3) and 1.938 (3) Å] in a planar geometry. The ten-coordinate Dy(III...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051998/ https://www.ncbi.nlm.nih.gov/pubmed/21522291 http://dx.doi.org/10.1107/S1600536811005253 |
| _version_ | 1782199602680692736 |
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| author | Xu, Lili Li, Hong-Feng Chen, Peng Yan, Peng-Fei |
| author_facet | Xu, Lili Li, Hong-Feng Chen, Peng Yan, Peng-Fei |
| author_sort | Xu, Lili |
| collection | PubMed |
| description | In the title heterodinuclear salen-type complex, [CuDy(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)OH, the copper(II) ion is tetracoordinated by two imino N atoms [Cu—N = 1.961 (4) and 1.968 (4) Å] and two phenolate O atoms [Cu—O = 1.931 (3) and 1.938 (3) Å] in a planar geometry. The ten-coordinate Dy(III) ion is ligated by six O atoms of three nitrate groups and four O atoms from the ligand [Dy—O = 2.368 (3)–2.601 (3) Å]. In the crystal, complex molecules and solvent molecules are linked by intermolecular O—H⋯O hydrogen bonds. |
| format | Text |
| id | pubmed-3051998 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30519982011-04-26 {μ-6,6′-Dimethoxy-2,2-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}trinitratocopper(II)dysprosium(III) methanol monosolvate Xu, Lili Li, Hong-Feng Chen, Peng Yan, Peng-Fei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title heterodinuclear salen-type complex, [CuDy(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)OH, the copper(II) ion is tetracoordinated by two imino N atoms [Cu—N = 1.961 (4) and 1.968 (4) Å] and two phenolate O atoms [Cu—O = 1.931 (3) and 1.938 (3) Å] in a planar geometry. The ten-coordinate Dy(III) ion is ligated by six O atoms of three nitrate groups and four O atoms from the ligand [Dy—O = 2.368 (3)–2.601 (3) Å]. In the crystal, complex molecules and solvent molecules are linked by intermolecular O—H⋯O hydrogen bonds. International Union of Crystallography 2011-02-23 /pmc/articles/PMC3051998/ /pubmed/21522291 http://dx.doi.org/10.1107/S1600536811005253 Text en © Xu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Xu, Lili Li, Hong-Feng Chen, Peng Yan, Peng-Fei {μ-6,6′-Dimethoxy-2,2-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}trinitratocopper(II)dysprosium(III) methanol monosolvate |
| title | {μ-6,6′-Dimethoxy-2,2-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}trinitratocopper(II)dysprosium(III) methanol monosolvate |
| title_full | {μ-6,6′-Dimethoxy-2,2-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}trinitratocopper(II)dysprosium(III) methanol monosolvate |
| title_fullStr | {μ-6,6′-Dimethoxy-2,2-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}trinitratocopper(II)dysprosium(III) methanol monosolvate |
| title_full_unstemmed | {μ-6,6′-Dimethoxy-2,2-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}trinitratocopper(II)dysprosium(III) methanol monosolvate |
| title_short | {μ-6,6′-Dimethoxy-2,2-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}trinitratocopper(II)dysprosium(III) methanol monosolvate |
| title_sort | {μ-6,6′-dimethoxy-2,2-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}trinitratocopper(ii)dysprosium(iii) methanol monosolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051998/ https://www.ncbi.nlm.nih.gov/pubmed/21522291 http://dx.doi.org/10.1107/S1600536811005253 |
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