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5,5′-Bis[(1H-imidazol-1-yl)methyl]-2,2′-bipyridine methanol disolvate
The title compound, C(18)H(16)N(6)·2CH(3)OH, was prepared by the reaction of 5,5′-bis(bromomethyl)-2,2′-bipyridine with imidazole. The main molecule lies on an inversion center located at the mid-point of the C—C bond joining the two pyridine rings. The asymmetric unit therefore contains one hal...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051999/ https://www.ncbi.nlm.nih.gov/pubmed/21522319 http://dx.doi.org/10.1107/S1600536811003643 |
Sumario: | The title compound, C(18)H(16)N(6)·2CH(3)OH, was prepared by the reaction of 5,5′-bis(bromomethyl)-2,2′-bipyridine with imidazole. The main molecule lies on an inversion center located at the mid-point of the C—C bond joining the two pyridine rings. The asymmetric unit therefore contains one half-molecule and one methanol solvent molecule. The dihedral angle between the pyridine and imidazole rings is 72.32 (5)°. In the crystal, weak intermolecular O—H⋯N, C—H⋯N and C—H⋯O hydrogen bonds contribute to the stabilization of the packing. |
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