Cargando…

5,5′-Bis[(1H-imidazol-1-yl)meth­yl]-2,2′-bipyridine methanol disolvate

The title compound, C(18)H(16)N(6)·2CH(3)OH, was prepared by the reaction of 5,5′-bis­(bromo­meth­yl)-2,2′-bipyridine with imidazole. The main mol­ecule lies on an inversion center located at the mid-point of the C—C bond joining the two pyridine rings. The asymmetric unit therefore contains one hal...

Descripción completa

Detalles Bibliográficos
Autores principales: Moon, Suk-Hee, Kim, Tae Ho, Park, Ki-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051999/
https://www.ncbi.nlm.nih.gov/pubmed/21522319
http://dx.doi.org/10.1107/S1600536811003643
Descripción
Sumario:The title compound, C(18)H(16)N(6)·2CH(3)OH, was prepared by the reaction of 5,5′-bis­(bromo­meth­yl)-2,2′-bipyridine with imidazole. The main mol­ecule lies on an inversion center located at the mid-point of the C—C bond joining the two pyridine rings. The asymmetric unit therefore contains one half-mol­ecule and one methanol solvent mol­ecule. The dihedral angle between the pyridine and imidazole rings is 72.32 (5)°. In the crystal, weak inter­molecular O—H⋯N, C—H⋯N and C—H⋯O hydrogen bonds contribute to the stabilization of the packing.