5,5′-Bis[(1H-imidazol-1-yl)meth­yl]-2,2′-bipyridine methanol disolvate

The title compound, C(18)H(16)N(6)·2CH(3)OH, was prepared by the reaction of 5,5′-bis­(bromo­meth­yl)-2,2′-bipyridine with imidazole. The main mol­ecule lies on an inversion center located at the mid-point of the C—C bond joining the two pyridine rings. The asymmetric unit therefore contains one hal...

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Detalles Bibliográficos
Autores principales: Moon, Suk-Hee, Kim, Tae Ho, Park, Ki-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051999/
https://www.ncbi.nlm.nih.gov/pubmed/21522319
http://dx.doi.org/10.1107/S1600536811003643
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author Moon, Suk-Hee
Kim, Tae Ho
Park, Ki-Min
author_facet Moon, Suk-Hee
Kim, Tae Ho
Park, Ki-Min
author_sort Moon, Suk-Hee
collection PubMed
description The title compound, C(18)H(16)N(6)·2CH(3)OH, was prepared by the reaction of 5,5′-bis­(bromo­meth­yl)-2,2′-bipyridine with imidazole. The main mol­ecule lies on an inversion center located at the mid-point of the C—C bond joining the two pyridine rings. The asymmetric unit therefore contains one half-mol­ecule and one methanol solvent mol­ecule. The dihedral angle between the pyridine and imidazole rings is 72.32 (5)°. In the crystal, weak inter­molecular O—H⋯N, C—H⋯N and C—H⋯O hydrogen bonds contribute to the stabilization of the packing.
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spelling pubmed-30519992011-04-26 5,5′-Bis[(1H-imidazol-1-yl)meth­yl]-2,2′-bipyridine methanol disolvate Moon, Suk-Hee Kim, Tae Ho Park, Ki-Min Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(16)N(6)·2CH(3)OH, was prepared by the reaction of 5,5′-bis­(bromo­meth­yl)-2,2′-bipyridine with imidazole. The main mol­ecule lies on an inversion center located at the mid-point of the C—C bond joining the two pyridine rings. The asymmetric unit therefore contains one half-mol­ecule and one methanol solvent mol­ecule. The dihedral angle between the pyridine and imidazole rings is 72.32 (5)°. In the crystal, weak inter­molecular O—H⋯N, C—H⋯N and C—H⋯O hydrogen bonds contribute to the stabilization of the packing. International Union of Crystallography 2011-02-02 /pmc/articles/PMC3051999/ /pubmed/21522319 http://dx.doi.org/10.1107/S1600536811003643 Text en © Moon et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Moon, Suk-Hee
Kim, Tae Ho
Park, Ki-Min
5,5′-Bis[(1H-imidazol-1-yl)meth­yl]-2,2′-bipyridine methanol disolvate
title 5,5′-Bis[(1H-imidazol-1-yl)meth­yl]-2,2′-bipyridine methanol disolvate
title_full 5,5′-Bis[(1H-imidazol-1-yl)meth­yl]-2,2′-bipyridine methanol disolvate
title_fullStr 5,5′-Bis[(1H-imidazol-1-yl)meth­yl]-2,2′-bipyridine methanol disolvate
title_full_unstemmed 5,5′-Bis[(1H-imidazol-1-yl)meth­yl]-2,2′-bipyridine methanol disolvate
title_short 5,5′-Bis[(1H-imidazol-1-yl)meth­yl]-2,2′-bipyridine methanol disolvate
title_sort 5,5′-bis[(1h-imidazol-1-yl)meth­yl]-2,2′-bipyridine methanol disolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051999/
https://www.ncbi.nlm.nih.gov/pubmed/21522319
http://dx.doi.org/10.1107/S1600536811003643
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AT parkkimin 55bis1himidazol1ylmethyl22bipyridinemethanoldisolvate

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