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catena-Poly[[[diaquacadmium]-μ-2,2′-(1,2-phenylenedioxy)diacetato] monohydrate]
In the title coordination complex, {[Cd(C(10)H(8)O(6))(H(2)O)(2)]·H(2)O}(n) the Cd(II) atom is seven-coordinated in a distorted pentagonal–bipyramidal geometry, the pentagonal plane comprising four O-atom donors from the 2,2′-(1,2-phenylenedioxy)diacetate chelate ligand together with a bridging...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052000/ https://www.ncbi.nlm.nih.gov/pubmed/21522271 http://dx.doi.org/10.1107/S1600536811004867 |
Sumario: | In the title coordination complex, {[Cd(C(10)H(8)O(6))(H(2)O)(2)]·H(2)O}(n) the Cd(II) atom is seven-coordinated in a distorted pentagonal–bipyramidal geometry, the pentagonal plane comprising four O-atom donors from the 2,2′-(1,2-phenylenedioxy)diacetate chelate ligand together with a bridging carboxylate O-atom donor, with the axial sites occupied by two water molecules. The resulting helical chains extend along the b axis and are interconnected by extensive O—H⋯O hydrogen-bonding interactions, which also involve the water molecule of solvation, giving a three-dimensional structure. |
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