catena-Poly[[[diaqua­cadmium]-μ-2,2′-(1,2-phenyl­enedi­oxy)diacetato] mono­hydrate]

In the title coordination complex, {[Cd(C(10)H(8)O(6))(H(2)O)(2)]·H(2)O}(n) the Cd(II) atom is seven-coordinated in a distorted penta­gonal–bipyramidal geometry, the penta­gonal plane comprising four O-atom donors from the 2,2′-(1,2-phenyl­enedi­oxy)diacetate chelate ligand together with a bridging...

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Detalles Bibliográficos
Autores principales: Hou, Huan-Fu, Zhang, Xiu-Ling
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052000/
https://www.ncbi.nlm.nih.gov/pubmed/21522271
http://dx.doi.org/10.1107/S1600536811004867
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author Hou, Huan-Fu
Zhang, Xiu-Ling
author_facet Hou, Huan-Fu
Zhang, Xiu-Ling
author_sort Hou, Huan-Fu
collection PubMed
description In the title coordination complex, {[Cd(C(10)H(8)O(6))(H(2)O)(2)]·H(2)O}(n) the Cd(II) atom is seven-coordinated in a distorted penta­gonal–bipyramidal geometry, the penta­gonal plane comprising four O-atom donors from the 2,2′-(1,2-phenyl­enedi­oxy)diacetate chelate ligand together with a bridging carboxyl­ate O-atom donor, with the axial sites occupied by two water mol­ecules. The resulting helical chains extend along the b axis and are inter­connected by extensive O—H⋯O hydrogen-bonding inter­actions, which also involve the water mol­ecule of solvation, giving a three-dimensional structure.
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spelling pubmed-30520002011-04-26 catena-Poly[[[diaqua­cadmium]-μ-2,2′-(1,2-phenyl­enedi­oxy)diacetato] mono­hydrate] Hou, Huan-Fu Zhang, Xiu-Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination complex, {[Cd(C(10)H(8)O(6))(H(2)O)(2)]·H(2)O}(n) the Cd(II) atom is seven-coordinated in a distorted penta­gonal–bipyramidal geometry, the penta­gonal plane comprising four O-atom donors from the 2,2′-(1,2-phenyl­enedi­oxy)diacetate chelate ligand together with a bridging carboxyl­ate O-atom donor, with the axial sites occupied by two water mol­ecules. The resulting helical chains extend along the b axis and are inter­connected by extensive O—H⋯O hydrogen-bonding inter­actions, which also involve the water mol­ecule of solvation, giving a three-dimensional structure. International Union of Crystallography 2011-02-16 /pmc/articles/PMC3052000/ /pubmed/21522271 http://dx.doi.org/10.1107/S1600536811004867 Text en © Hou and Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hou, Huan-Fu
Zhang, Xiu-Ling
catena-Poly[[[diaqua­cadmium]-μ-2,2′-(1,2-phenyl­enedi­oxy)diacetato] mono­hydrate]
title catena-Poly[[[diaqua­cadmium]-μ-2,2′-(1,2-phenyl­enedi­oxy)diacetato] mono­hydrate]
title_full catena-Poly[[[diaqua­cadmium]-μ-2,2′-(1,2-phenyl­enedi­oxy)diacetato] mono­hydrate]
title_fullStr catena-Poly[[[diaqua­cadmium]-μ-2,2′-(1,2-phenyl­enedi­oxy)diacetato] mono­hydrate]
title_full_unstemmed catena-Poly[[[diaqua­cadmium]-μ-2,2′-(1,2-phenyl­enedi­oxy)diacetato] mono­hydrate]
title_short catena-Poly[[[diaqua­cadmium]-μ-2,2′-(1,2-phenyl­enedi­oxy)diacetato] mono­hydrate]
title_sort catena-poly[[[diaqua­cadmium]-μ-2,2′-(1,2-phenyl­enedi­oxy)diacetato] mono­hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052000/
https://www.ncbi.nlm.nih.gov/pubmed/21522271
http://dx.doi.org/10.1107/S1600536811004867
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AT zhangxiuling catenapolydiaquacadmiumm2212phenylenedioxydiacetatomonohydrate

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