catena-Poly[[[(2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)(nitrato-κ(2) O,O′)bis­muth(III)]-μ-5-carb­oxy­benzene-1,3-dicarboxyl­ato-κ(4) O (1) ,O (1′) :O (3) ,O (3′)] dimethyl sulfoxide monosolvate]

The polymeric title compound, {[Bi(C(9)H(4)O(6))(NO(3))(C(10)H(8)N(2))(C(2)H(6)OS)]·C(2)H(6)OS}(n), was obtained by the reaction of bis­muth(III) nitrate, bipyridine (bpy) and 1,3,5-benzene­tricarb­oxy­lic acid (H(3)BTC). The Bi(III) ion is coordinated in a distorted tricapped trigonal-prismatic geo...

Descripción completa

Detalles Bibliográficos
Autores principales: Pasdar, Hoda, Namegh, Marjan, Aghabozorg, Hossein, Notash, Behrouz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052002/
https://www.ncbi.nlm.nih.gov/pubmed/21522282
http://dx.doi.org/10.1107/S1600536811005745
_version_ 1782199603695714304
author Pasdar, Hoda
Namegh, Marjan
Aghabozorg, Hossein
Notash, Behrouz
author_facet Pasdar, Hoda
Namegh, Marjan
Aghabozorg, Hossein
Notash, Behrouz
author_sort Pasdar, Hoda
collection PubMed
description The polymeric title compound, {[Bi(C(9)H(4)O(6))(NO(3))(C(10)H(8)N(2))(C(2)H(6)OS)]·C(2)H(6)OS}(n), was obtained by the reaction of bis­muth(III) nitrate, bipyridine (bpy) and 1,3,5-benzene­tricarb­oxy­lic acid (H(3)BTC). The Bi(III) ion is coordinated in a distorted tricapped trigonal-prismatic geometry, defined by two N atoms of the bipy ligand, four O atoms of two HBTC(2−) anions, two O atoms of a nitrate anion and one O atom of a dimethyl sulfoxide ligand. The crystal packing is stabilized by O—H⋯O and C—H⋯O hydrogen bonds. The S atom of the non-coordinating dimethyl sulfoxide mol­ecule is disordered over two sets of sites with refined site-occupancies of 0.430 (19) and 0.570 (19).
format Text
id pubmed-3052002
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30520022011-04-26 catena-Poly[[[(2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)(nitrato-κ(2) O,O′)bis­muth(III)]-μ-5-carb­oxy­benzene-1,3-dicarboxyl­ato-κ(4) O (1) ,O (1′) :O (3) ,O (3′)] dimethyl sulfoxide monosolvate] Pasdar, Hoda Namegh, Marjan Aghabozorg, Hossein Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The polymeric title compound, {[Bi(C(9)H(4)O(6))(NO(3))(C(10)H(8)N(2))(C(2)H(6)OS)]·C(2)H(6)OS}(n), was obtained by the reaction of bis­muth(III) nitrate, bipyridine (bpy) and 1,3,5-benzene­tricarb­oxy­lic acid (H(3)BTC). The Bi(III) ion is coordinated in a distorted tricapped trigonal-prismatic geometry, defined by two N atoms of the bipy ligand, four O atoms of two HBTC(2−) anions, two O atoms of a nitrate anion and one O atom of a dimethyl sulfoxide ligand. The crystal packing is stabilized by O—H⋯O and C—H⋯O hydrogen bonds. The S atom of the non-coordinating dimethyl sulfoxide mol­ecule is disordered over two sets of sites with refined site-occupancies of 0.430 (19) and 0.570 (19). International Union of Crystallography 2011-02-19 /pmc/articles/PMC3052002/ /pubmed/21522282 http://dx.doi.org/10.1107/S1600536811005745 Text en © Pasdar et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Pasdar, Hoda
Namegh, Marjan
Aghabozorg, Hossein
Notash, Behrouz
catena-Poly[[[(2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)(nitrato-κ(2) O,O′)bis­muth(III)]-μ-5-carb­oxy­benzene-1,3-dicarboxyl­ato-κ(4) O (1) ,O (1′) :O (3) ,O (3′)] dimethyl sulfoxide monosolvate]
title catena-Poly[[[(2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)(nitrato-κ(2) O,O′)bis­muth(III)]-μ-5-carb­oxy­benzene-1,3-dicarboxyl­ato-κ(4) O (1) ,O (1′) :O (3) ,O (3′)] dimethyl sulfoxide monosolvate]
title_full catena-Poly[[[(2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)(nitrato-κ(2) O,O′)bis­muth(III)]-μ-5-carb­oxy­benzene-1,3-dicarboxyl­ato-κ(4) O (1) ,O (1′) :O (3) ,O (3′)] dimethyl sulfoxide monosolvate]
title_fullStr catena-Poly[[[(2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)(nitrato-κ(2) O,O′)bis­muth(III)]-μ-5-carb­oxy­benzene-1,3-dicarboxyl­ato-κ(4) O (1) ,O (1′) :O (3) ,O (3′)] dimethyl sulfoxide monosolvate]
title_full_unstemmed catena-Poly[[[(2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)(nitrato-κ(2) O,O′)bis­muth(III)]-μ-5-carb­oxy­benzene-1,3-dicarboxyl­ato-κ(4) O (1) ,O (1′) :O (3) ,O (3′)] dimethyl sulfoxide monosolvate]
title_short catena-Poly[[[(2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)(nitrato-κ(2) O,O′)bis­muth(III)]-μ-5-carb­oxy­benzene-1,3-dicarboxyl­ato-κ(4) O (1) ,O (1′) :O (3) ,O (3′)] dimethyl sulfoxide monosolvate]
title_sort catena-poly[[[(2,2′-bipyridine-κ(2) n,n′)(dimethyl sulfoxide-κo)(nitrato-κ(2) o,o′)bis­muth(iii)]-μ-5-carb­oxy­benzene-1,3-dicarboxyl­ato-κ(4) o (1) ,o (1′) :o (3) ,o (3′)] dimethyl sulfoxide monosolvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052002/
https://www.ncbi.nlm.nih.gov/pubmed/21522282
http://dx.doi.org/10.1107/S1600536811005745
work_keys_str_mv AT pasdarhoda catenapoly22bipyridinek2nndimethylsulfoxidekonitratok2oobismuthiiim5carboxybenzene13dicarboxylatok4o1o1o3o3dimethylsulfoxidemonosolvate
AT nameghmarjan catenapoly22bipyridinek2nndimethylsulfoxidekonitratok2oobismuthiiim5carboxybenzene13dicarboxylatok4o1o1o3o3dimethylsulfoxidemonosolvate
AT aghabozorghossein catenapoly22bipyridinek2nndimethylsulfoxidekonitratok2oobismuthiiim5carboxybenzene13dicarboxylatok4o1o1o3o3dimethylsulfoxidemonosolvate
AT notashbehrouz catenapoly22bipyridinek2nndimethylsulfoxidekonitratok2oobismuthiiim5carboxybenzene13dicarboxylatok4o1o1o3o3dimethylsulfoxidemonosolvate

Ejemplares similares