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(η(4)-s-cis-1,3-Butadiene)tetracarbonylchromium(0)
In the title complex, [Cr(C(4)H(6))(CO)(4)], the Cr(0) atom shows a distorted octahedral environment from four C atoms of the carbonyl ligands and the two π-bonds of the s-cis-1,3-butadiene ligand. The complex has an approximate non-crystallographic mirror symmetry m passing through the chromium at...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052012/ https://www.ncbi.nlm.nih.gov/pubmed/21522264 http://dx.doi.org/10.1107/S1600536811004636 |
| _version_ | 1782199606267871232 |
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| author | Reiss, Guido J. Finze, Maik |
| author_facet | Reiss, Guido J. Finze, Maik |
| author_sort | Reiss, Guido J. |
| collection | PubMed |
| description | In the title complex, [Cr(C(4)H(6))(CO)(4)], the Cr(0) atom shows a distorted octahedral environment from four C atoms of the carbonyl ligands and the two π-bonds of the s-cis-1,3-butadiene ligand. The complex has an approximate non-crystallographic mirror symmetry m passing through the chromium atom, two carbonyl ligands and the mid-point of the central C—C bond of the s-cis-1,3-butadiene ligand. The C—C bond lengths in the s-cis-1,3-butadiene ligand alternate, the terminal distances being shorter than the central distance. |
| format | Text |
| id | pubmed-3052012 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30520122011-04-26 (η(4)-s-cis-1,3-Butadiene)tetracarbonylchromium(0) Reiss, Guido J. Finze, Maik Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cr(C(4)H(6))(CO)(4)], the Cr(0) atom shows a distorted octahedral environment from four C atoms of the carbonyl ligands and the two π-bonds of the s-cis-1,3-butadiene ligand. The complex has an approximate non-crystallographic mirror symmetry m passing through the chromium atom, two carbonyl ligands and the mid-point of the central C—C bond of the s-cis-1,3-butadiene ligand. The C—C bond lengths in the s-cis-1,3-butadiene ligand alternate, the terminal distances being shorter than the central distance. International Union of Crystallography 2011-02-12 /pmc/articles/PMC3052012/ /pubmed/21522264 http://dx.doi.org/10.1107/S1600536811004636 Text en © Reiss and Finze 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Reiss, Guido J. Finze, Maik (η(4)-s-cis-1,3-Butadiene)tetracarbonylchromium(0) |
| title | (η(4)-s-cis-1,3-Butadiene)tetracarbonylchromium(0) |
| title_full | (η(4)-s-cis-1,3-Butadiene)tetracarbonylchromium(0) |
| title_fullStr | (η(4)-s-cis-1,3-Butadiene)tetracarbonylchromium(0) |
| title_full_unstemmed | (η(4)-s-cis-1,3-Butadiene)tetracarbonylchromium(0) |
| title_short | (η(4)-s-cis-1,3-Butadiene)tetracarbonylchromium(0) |
| title_sort | (η(4)-s-cis-1,3-butadiene)tetracarbonylchromium(0) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052012/ https://www.ncbi.nlm.nih.gov/pubmed/21522264 http://dx.doi.org/10.1107/S1600536811004636 |
| work_keys_str_mv | AT reissguidoj ē4scis13butadienetetracarbonylchromium0 AT finzemaik ē4scis13butadienetetracarbonylchromium0 |