Bis(3-carb­oxy-5-nitro­benzoato)bis­[2-(pyridin-4-yl)-1H-imidazo[4,5-f][1,10]phenanthroline]manganese(II)

In the title compound, [Mn(C(8)H(4)NO(6))(2)(C(18)H(11)N(5))(2)], the Mn(II) atom is six-coordinated by two N,N′-bidentate 6-(pyridin-4-yl)-5H-cyclo­penta­[f][1,10]phenanthroline (pcp) ligands and two carboxyl­ate O atoms from two monodentate 3-carb­oxy-5-nitro­benzoate anions in a distorted cis-MnO...

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Detalles Bibliográficos
Autores principales: Xu, Hong-Bin, Ma, Shuai, He, Yu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052015/
https://www.ncbi.nlm.nih.gov/pubmed/21522257
http://dx.doi.org/10.1107/S1600536811004569
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author Xu, Hong-Bin
Ma, Shuai
He, Yu
author_facet Xu, Hong-Bin
Ma, Shuai
He, Yu
author_sort Xu, Hong-Bin
collection PubMed
description In the title compound, [Mn(C(8)H(4)NO(6))(2)(C(18)H(11)N(5))(2)], the Mn(II) atom is six-coordinated by two N,N′-bidentate 6-(pyridin-4-yl)-5H-cyclo­penta­[f][1,10]phenanthroline (pcp) ligands and two carboxyl­ate O atoms from two monodentate 3-carb­oxy-5-nitro­benzoate anions in a distorted cis-MnO(2)N(4) octa­hedral arrangement. Within the pcp ligands, the dihedral angles between the polycyclic skeletons and pendant pyridine rings are 6.2 (2) and 8.3 (2)°. In the crystal, mol­ecules are linked by O—H⋯N and N—H⋯O hydrogen bonds. Several aromatic π–π stacking inter­actions [shortest centroid–centroid separation = 3.516 (3) Å] are also observed.
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spelling pubmed-30520152011-04-26 Bis(3-carb­oxy-5-nitro­benzoato)bis­[2-(pyridin-4-yl)-1H-imidazo[4,5-f][1,10]phenanthroline]manganese(II) Xu, Hong-Bin Ma, Shuai He, Yu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(8)H(4)NO(6))(2)(C(18)H(11)N(5))(2)], the Mn(II) atom is six-coordinated by two N,N′-bidentate 6-(pyridin-4-yl)-5H-cyclo­penta­[f][1,10]phenanthroline (pcp) ligands and two carboxyl­ate O atoms from two monodentate 3-carb­oxy-5-nitro­benzoate anions in a distorted cis-MnO(2)N(4) octa­hedral arrangement. Within the pcp ligands, the dihedral angles between the polycyclic skeletons and pendant pyridine rings are 6.2 (2) and 8.3 (2)°. In the crystal, mol­ecules are linked by O—H⋯N and N—H⋯O hydrogen bonds. Several aromatic π–π stacking inter­actions [shortest centroid–centroid separation = 3.516 (3) Å] are also observed. International Union of Crystallography 2011-02-12 /pmc/articles/PMC3052015/ /pubmed/21522257 http://dx.doi.org/10.1107/S1600536811004569 Text en © Xu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Hong-Bin
Ma, Shuai
He, Yu
Bis(3-carb­oxy-5-nitro­benzoato)bis­[2-(pyridin-4-yl)-1H-imidazo[4,5-f][1,10]phenanthroline]manganese(II)
title Bis(3-carb­oxy-5-nitro­benzoato)bis­[2-(pyridin-4-yl)-1H-imidazo[4,5-f][1,10]phenanthroline]manganese(II)
title_full Bis(3-carb­oxy-5-nitro­benzoato)bis­[2-(pyridin-4-yl)-1H-imidazo[4,5-f][1,10]phenanthroline]manganese(II)
title_fullStr Bis(3-carb­oxy-5-nitro­benzoato)bis­[2-(pyridin-4-yl)-1H-imidazo[4,5-f][1,10]phenanthroline]manganese(II)
title_full_unstemmed Bis(3-carb­oxy-5-nitro­benzoato)bis­[2-(pyridin-4-yl)-1H-imidazo[4,5-f][1,10]phenanthroline]manganese(II)
title_short Bis(3-carb­oxy-5-nitro­benzoato)bis­[2-(pyridin-4-yl)-1H-imidazo[4,5-f][1,10]phenanthroline]manganese(II)
title_sort bis(3-carb­oxy-5-nitro­benzoato)bis­[2-(pyridin-4-yl)-1h-imidazo[4,5-f][1,10]phenanthroline]manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052015/
https://www.ncbi.nlm.nih.gov/pubmed/21522257
http://dx.doi.org/10.1107/S1600536811004569
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AT heyu bis3carboxy5nitrobenzoatobis2pyridin4yl1himidazo45f110phenanthrolinemanganeseii

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