Dibromido{2-(morpholin-4-yl)-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}cadmium

The Cd(II) ion in the title compound, [CdBr(2)(C(13)H(19)N(3)O)], is five-coordinated by the N,N′,N′′-tridentate Schiff base ligand and two Br atoms in a distorted square-pyramidal geometry. In the crystal, inter­molecular C—H⋯O and C—H⋯Br hydrogen bonds link adjacent mol­ecules into layers parallel...

Descripción completa

Detalles Bibliográficos
Autores principales: Suleiman Gwaram, Nura, Khaledi, Hamid, Mohd Ali, Hapipah
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052017/
https://www.ncbi.nlm.nih.gov/pubmed/21522276
http://dx.doi.org/10.1107/S160053681100554X
_version_ 1782199607484219392
author Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
author_facet Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
author_sort Suleiman Gwaram, Nura
collection PubMed
description The Cd(II) ion in the title compound, [CdBr(2)(C(13)H(19)N(3)O)], is five-coordinated by the N,N′,N′′-tridentate Schiff base ligand and two Br atoms in a distorted square-pyramidal geometry. In the crystal, inter­molecular C—H⋯O and C—H⋯Br hydrogen bonds link adjacent mol­ecules into layers parallel to the ab plane. An intra­molecular C—H⋯Br inter­action is also observed.
format Text
id pubmed-3052017
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30520172011-04-26 Dibromido{2-(morpholin-4-yl)-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}cadmium Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cd(II) ion in the title compound, [CdBr(2)(C(13)H(19)N(3)O)], is five-coordinated by the N,N′,N′′-tridentate Schiff base ligand and two Br atoms in a distorted square-pyramidal geometry. In the crystal, inter­molecular C—H⋯O and C—H⋯Br hydrogen bonds link adjacent mol­ecules into layers parallel to the ab plane. An intra­molecular C—H⋯Br inter­action is also observed. International Union of Crystallography 2011-02-19 /pmc/articles/PMC3052017/ /pubmed/21522276 http://dx.doi.org/10.1107/S160053681100554X Text en © Suleiman Gwaram et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
Dibromido{2-(morpholin-4-yl)-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}cadmium
title Dibromido{2-(morpholin-4-yl)-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}cadmium
title_full Dibromido{2-(morpholin-4-yl)-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}cadmium
title_fullStr Dibromido{2-(morpholin-4-yl)-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}cadmium
title_full_unstemmed Dibromido{2-(morpholin-4-yl)-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}cadmium
title_short Dibromido{2-(morpholin-4-yl)-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}cadmium
title_sort dibromido{2-(morpholin-4-yl)-n-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) n,n′,n′′}cadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052017/
https://www.ncbi.nlm.nih.gov/pubmed/21522276
http://dx.doi.org/10.1107/S160053681100554X
work_keys_str_mv AT suleimangwaramnura dibromido2morpholin4yln12pyridylethylideneethanaminek3nnncadmium
AT khaledihamid dibromido2morpholin4yln12pyridylethylideneethanaminek3nnncadmium
AT mohdalihapipah dibromido2morpholin4yln12pyridylethylideneethanaminek3nnncadmium

Ejemplares similares