(6,6′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)diiodidomercury(II)

In the title complex, [HgI(2)(C(12)H(12)N(2))], the Hg(II) atom has a distorted tetra­hedral coordination formed by two N atoms of the 6,6′-dimethyl-2,2′-bipyridine ligand and two terminal I atoms [N—Hg—N = 70.1 (2) and I—Hg—I = 130.59 (3)°]. The crystal packing features π–π contacts between the pyr...

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Detalles Bibliográficos
Autores principales: Alizadeh, Robabeh, Seifi, Sara, Amani, Vahid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052018/
https://www.ncbi.nlm.nih.gov/pubmed/21522242
http://dx.doi.org/10.1107/S1600536811004041
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author Alizadeh, Robabeh
Seifi, Sara
Amani, Vahid
author_facet Alizadeh, Robabeh
Seifi, Sara
Amani, Vahid
author_sort Alizadeh, Robabeh
collection PubMed
description In the title complex, [HgI(2)(C(12)H(12)N(2))], the Hg(II) atom has a distorted tetra­hedral coordination formed by two N atoms of the 6,6′-dimethyl-2,2′-bipyridine ligand and two terminal I atoms [N—Hg—N = 70.1 (2) and I—Hg—I = 130.59 (3)°]. The crystal packing features π–π contacts between the pyridine rings of adjacent mol­ecules [centroid–centroid distance = 3.773 (5) Å] and also between a pyridine ring of one mol­ecule and the five-membered chelate ring of an adjacent mol­ecule [centroid–centroid distance = 3.668 (4) Å].
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spelling pubmed-30520182011-04-26 (6,6′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)diiodidomercury(II) Alizadeh, Robabeh Seifi, Sara Amani, Vahid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [HgI(2)(C(12)H(12)N(2))], the Hg(II) atom has a distorted tetra­hedral coordination formed by two N atoms of the 6,6′-dimethyl-2,2′-bipyridine ligand and two terminal I atoms [N—Hg—N = 70.1 (2) and I—Hg—I = 130.59 (3)°]. The crystal packing features π–π contacts between the pyridine rings of adjacent mol­ecules [centroid–centroid distance = 3.773 (5) Å] and also between a pyridine ring of one mol­ecule and the five-membered chelate ring of an adjacent mol­ecule [centroid–centroid distance = 3.668 (4) Å]. International Union of Crystallography 2011-02-05 /pmc/articles/PMC3052018/ /pubmed/21522242 http://dx.doi.org/10.1107/S1600536811004041 Text en © Alizadeh et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Alizadeh, Robabeh
Seifi, Sara
Amani, Vahid
(6,6′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)diiodidomercury(II)
title (6,6′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)diiodidomercury(II)
title_full (6,6′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)diiodidomercury(II)
title_fullStr (6,6′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)diiodidomercury(II)
title_full_unstemmed (6,6′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)diiodidomercury(II)
title_short (6,6′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)diiodidomercury(II)
title_sort (6,6′-dimethyl-2,2′-bipyridine-κ(2) n,n′)diiodidomercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052018/
https://www.ncbi.nlm.nih.gov/pubmed/21522242
http://dx.doi.org/10.1107/S1600536811004041
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AT seifisara 66dimethyl22bipyridinek2nndiiodidomercuryii
AT amanivahid 66dimethyl22bipyridinek2nndiiodidomercuryii

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