Methidathion: S-(5-meth­oxy-2-oxo-2,3-dihydro-1,3,4-thia­diazol-3-yl)methyl O,O-dimethyl phospho­rodithio­ate

The title compound, C(6)H(11)N(2)O(4)PS(3), crystallizes with two independent mol­ecules in the asymmetric unit. The dihedral angles between the thia­diazole ring planes and the PS(2) planes of the phospho­rodithio­ate group are 86.51 (5) and 56.33 (5)° in the two mol­ecules. In the crystal, weak in...

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Detalles Bibliográficos
Autores principales: Kim, Hyunjee, Shin, Yong Woon, Park, Ki-Min, Kim, Jineun, Kim, Tae Ho
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052021/
https://www.ncbi.nlm.nih.gov/pubmed/21522405
http://dx.doi.org/10.1107/S1600536811005241
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author Kim, Hyunjee
Shin, Yong Woon
Park, Ki-Min
Kim, Jineun
Kim, Tae Ho
author_facet Kim, Hyunjee
Shin, Yong Woon
Park, Ki-Min
Kim, Jineun
Kim, Tae Ho
author_sort Kim, Hyunjee
collection PubMed
description The title compound, C(6)H(11)N(2)O(4)PS(3), crystallizes with two independent mol­ecules in the asymmetric unit. The dihedral angles between the thia­diazole ring planes and the PS(2) planes of the phospho­rodithio­ate group are 86.51 (5) and 56.33 (5)° in the two mol­ecules. In the crystal, weak inter­molecular S⋯S [3.570 (8) Å] inter­actions and C—H⋯O and C—H⋯N hydrogen bonds contribute to the stabilization of the packing.
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spelling pubmed-30520212011-04-26 Methidathion: S-(5-meth­oxy-2-oxo-2,3-dihydro-1,3,4-thia­diazol-3-yl)methyl O,O-dimethyl phospho­rodithio­ate Kim, Hyunjee Shin, Yong Woon Park, Ki-Min Kim, Jineun Kim, Tae Ho Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(6)H(11)N(2)O(4)PS(3), crystallizes with two independent mol­ecules in the asymmetric unit. The dihedral angles between the thia­diazole ring planes and the PS(2) planes of the phospho­rodithio­ate group are 86.51 (5) and 56.33 (5)° in the two mol­ecules. In the crystal, weak inter­molecular S⋯S [3.570 (8) Å] inter­actions and C—H⋯O and C—H⋯N hydrogen bonds contribute to the stabilization of the packing. International Union of Crystallography 2011-02-19 /pmc/articles/PMC3052021/ /pubmed/21522405 http://dx.doi.org/10.1107/S1600536811005241 Text en © Kim et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kim, Hyunjee
Shin, Yong Woon
Park, Ki-Min
Kim, Jineun
Kim, Tae Ho
Methidathion: S-(5-meth­oxy-2-oxo-2,3-dihydro-1,3,4-thia­diazol-3-yl)methyl O,O-dimethyl phospho­rodithio­ate
title Methidathion: S-(5-meth­oxy-2-oxo-2,3-dihydro-1,3,4-thia­diazol-3-yl)methyl O,O-dimethyl phospho­rodithio­ate
title_full Methidathion: S-(5-meth­oxy-2-oxo-2,3-dihydro-1,3,4-thia­diazol-3-yl)methyl O,O-dimethyl phospho­rodithio­ate
title_fullStr Methidathion: S-(5-meth­oxy-2-oxo-2,3-dihydro-1,3,4-thia­diazol-3-yl)methyl O,O-dimethyl phospho­rodithio­ate
title_full_unstemmed Methidathion: S-(5-meth­oxy-2-oxo-2,3-dihydro-1,3,4-thia­diazol-3-yl)methyl O,O-dimethyl phospho­rodithio­ate
title_short Methidathion: S-(5-meth­oxy-2-oxo-2,3-dihydro-1,3,4-thia­diazol-3-yl)methyl O,O-dimethyl phospho­rodithio­ate
title_sort methidathion: s-(5-meth­oxy-2-oxo-2,3-dihydro-1,3,4-thia­diazol-3-yl)methyl o,o-dimethyl phospho­rodithio­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052021/
https://www.ncbi.nlm.nih.gov/pubmed/21522405
http://dx.doi.org/10.1107/S1600536811005241
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AT kimtaeho methidathions5methoxy2oxo23dihydro134thiadiazol3ylmethyloodimethylphosphorodithioate

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