(1-Phenyl­sulfonyl-1H-indol-2-yl)(thio­phen-2-yl)methanone

The crystal studied of the title compound, C(19)H(13)NO(3)S(2), was found to be a non-merohedral twin with a domain ratio of 0.877 (3):0.123 (3). There are two independent mol­ecules in the asymmetric unit. The dihedral angles between the mean plane of the indole ring system and the phenyl­sulfonyl...

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Autores principales: KamalaKumar, C., Dhayalan, V., Mohanakrishnan, A. K., Balasubramanian, V., Manivannan, V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052024/
https://www.ncbi.nlm.nih.gov/pubmed/21522480
http://dx.doi.org/10.1107/S1600536811005666
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author KamalaKumar, C.
Dhayalan, V.
Mohanakrishnan, A. K.
Balasubramanian, V.
Manivannan, V.
author_facet KamalaKumar, C.
Dhayalan, V.
Mohanakrishnan, A. K.
Balasubramanian, V.
Manivannan, V.
author_sort KamalaKumar, C.
collection PubMed
description The crystal studied of the title compound, C(19)H(13)NO(3)S(2), was found to be a non-merohedral twin with a domain ratio of 0.877 (3):0.123 (3). There are two independent mol­ecules in the asymmetric unit. The dihedral angles between the mean plane of the indole ring system and the phenyl­sulfonyl ring are 71.67 (13) and 71.95 (13)° in the two mol­ecules while the indole unit and the thiophene ring make dihedral angles of 54.91 (12) and 56.92 (13)° in the two molecules. The crystal packing is stabilized by weak C—H⋯π inter­actions.
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spelling pubmed-30520242011-04-26 (1-Phenyl­sulfonyl-1H-indol-2-yl)(thio­phen-2-yl)methanone KamalaKumar, C. Dhayalan, V. Mohanakrishnan, A. K. Balasubramanian, V. Manivannan, V. Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal studied of the title compound, C(19)H(13)NO(3)S(2), was found to be a non-merohedral twin with a domain ratio of 0.877 (3):0.123 (3). There are two independent mol­ecules in the asymmetric unit. The dihedral angles between the mean plane of the indole ring system and the phenyl­sulfonyl ring are 71.67 (13) and 71.95 (13)° in the two mol­ecules while the indole unit and the thiophene ring make dihedral angles of 54.91 (12) and 56.92 (13)° in the two molecules. The crystal packing is stabilized by weak C—H⋯π inter­actions. International Union of Crystallography 2011-02-26 /pmc/articles/PMC3052024/ /pubmed/21522480 http://dx.doi.org/10.1107/S1600536811005666 Text en © KamalaKumar et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
KamalaKumar, C.
Dhayalan, V.
Mohanakrishnan, A. K.
Balasubramanian, V.
Manivannan, V.
(1-Phenyl­sulfonyl-1H-indol-2-yl)(thio­phen-2-yl)methanone
title (1-Phenyl­sulfonyl-1H-indol-2-yl)(thio­phen-2-yl)methanone
title_full (1-Phenyl­sulfonyl-1H-indol-2-yl)(thio­phen-2-yl)methanone
title_fullStr (1-Phenyl­sulfonyl-1H-indol-2-yl)(thio­phen-2-yl)methanone
title_full_unstemmed (1-Phenyl­sulfonyl-1H-indol-2-yl)(thio­phen-2-yl)methanone
title_short (1-Phenyl­sulfonyl-1H-indol-2-yl)(thio­phen-2-yl)methanone
title_sort (1-phenyl­sulfonyl-1h-indol-2-yl)(thio­phen-2-yl)methanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052024/
https://www.ncbi.nlm.nih.gov/pubmed/21522480
http://dx.doi.org/10.1107/S1600536811005666
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AT mohanakrishnanak 1phenylsulfonyl1hindol2ylthiophen2ylmethanone
AT balasubramanianv 1phenylsulfonyl1hindol2ylthiophen2ylmethanone
AT manivannanv 1phenylsulfonyl1hindol2ylthiophen2ylmethanone

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