(E)-Ethyl 2-cyano-3-[4-(4,5-diphenyl-1H-imidazol-2-yl)phen­yl]acrylate dihydrate

In the title compound, C(27)H(21)N(3)O(2)·2H(2)O, the three benzene rings attached to the heterocyclic imidazole ring are not coplanar with the latter, making dihedral angles of 14.8 (2), 31.4 (2), and 37.5 (2)°, respectively, for the benzene ring planes in the 2-, 4- and 5-positions. In the crystal...

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Detalles Bibliográficos
Autores principales: Liao, Wei-Xing, Peng, Yi-Wen, Yu, Li, Ning, Xiao-Qing, Zeng, He-Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052040/
https://www.ncbi.nlm.nih.gov/pubmed/21522450
http://dx.doi.org/10.1107/S1600536811006039
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author Liao, Wei-Xing
Peng, Yi-Wen
Yu, Li
Ning, Xiao-Qing
Zeng, He-Ping
author_facet Liao, Wei-Xing
Peng, Yi-Wen
Yu, Li
Ning, Xiao-Qing
Zeng, He-Ping
author_sort Liao, Wei-Xing
collection PubMed
description In the title compound, C(27)H(21)N(3)O(2)·2H(2)O, the three benzene rings attached to the heterocyclic imidazole ring are not coplanar with the latter, making dihedral angles of 14.8 (2), 31.4 (2), and 37.5 (2)°, respectively, for the benzene ring planes in the 2-, 4- and 5-positions. In the crystal, there are two water mol­ecules which serve as connectors between the acrylate mol­ecules and stabilize the structure via N—H⋯O, O—H⋯N, C—H⋯O and O—H⋯O hydrogen bonding.
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spelling pubmed-30520402011-04-26 (E)-Ethyl 2-cyano-3-[4-(4,5-diphenyl-1H-imidazol-2-yl)phen­yl]acrylate dihydrate Liao, Wei-Xing Peng, Yi-Wen Yu, Li Ning, Xiao-Qing Zeng, He-Ping Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(27)H(21)N(3)O(2)·2H(2)O, the three benzene rings attached to the heterocyclic imidazole ring are not coplanar with the latter, making dihedral angles of 14.8 (2), 31.4 (2), and 37.5 (2)°, respectively, for the benzene ring planes in the 2-, 4- and 5-positions. In the crystal, there are two water mol­ecules which serve as connectors between the acrylate mol­ecules and stabilize the structure via N—H⋯O, O—H⋯N, C—H⋯O and O—H⋯O hydrogen bonding. International Union of Crystallography 2011-02-26 /pmc/articles/PMC3052040/ /pubmed/21522450 http://dx.doi.org/10.1107/S1600536811006039 Text en © Liao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liao, Wei-Xing
Peng, Yi-Wen
Yu, Li
Ning, Xiao-Qing
Zeng, He-Ping
(E)-Ethyl 2-cyano-3-[4-(4,5-diphenyl-1H-imidazol-2-yl)phen­yl]acrylate dihydrate
title (E)-Ethyl 2-cyano-3-[4-(4,5-diphenyl-1H-imidazol-2-yl)phen­yl]acrylate dihydrate
title_full (E)-Ethyl 2-cyano-3-[4-(4,5-diphenyl-1H-imidazol-2-yl)phen­yl]acrylate dihydrate
title_fullStr (E)-Ethyl 2-cyano-3-[4-(4,5-diphenyl-1H-imidazol-2-yl)phen­yl]acrylate dihydrate
title_full_unstemmed (E)-Ethyl 2-cyano-3-[4-(4,5-diphenyl-1H-imidazol-2-yl)phen­yl]acrylate dihydrate
title_short (E)-Ethyl 2-cyano-3-[4-(4,5-diphenyl-1H-imidazol-2-yl)phen­yl]acrylate dihydrate
title_sort (e)-ethyl 2-cyano-3-[4-(4,5-diphenyl-1h-imidazol-2-yl)phen­yl]acrylate dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052040/
https://www.ncbi.nlm.nih.gov/pubmed/21522450
http://dx.doi.org/10.1107/S1600536811006039
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