[N-((E)-2-{[2-(Dimethyl­amino)­eth­yl]imino­meth­yl}phen­yl)-N-(2,6-dimethyl­phen­yl)anilinido-κ(3) N,N′,N′′]ethyl­zinc

The title eth­yl–zinc complex, [Zn(C(2)H(5))(C(19)H(24)N(3))], bears a tridentate anilinide–aldimine ligand and features one long Zn—N(amine) bond length, attributable to the crowded environment of the coordinated metal, arising from the dimethyl­phenyl group. The Zn(II) ion adopts a distorted tetra...

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Detalles Bibliográficos
Autores principales: Issa-Madongo, Mathurin, Mu, Ying
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052042/
https://www.ncbi.nlm.nih.gov/pubmed/21522288
http://dx.doi.org/10.1107/S1600536811005514
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author Issa-Madongo, Mathurin
Mu, Ying
author_facet Issa-Madongo, Mathurin
Mu, Ying
author_sort Issa-Madongo, Mathurin
collection PubMed
description The title eth­yl–zinc complex, [Zn(C(2)H(5))(C(19)H(24)N(3))], bears a tridentate anilinide–aldimine ligand and features one long Zn—N(amine) bond length, attributable to the crowded environment of the coordinated metal, arising from the dimethyl­phenyl group. The Zn(II) ion adopts a distorted tetra­hedral geometry, the dihedral angle between the two benzene rings being 86.05 (16)°.
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spelling pubmed-30520422011-04-26 [N-((E)-2-{[2-(Dimethyl­amino)­eth­yl]imino­meth­yl}phen­yl)-N-(2,6-dimethyl­phen­yl)anilinido-κ(3) N,N′,N′′]ethyl­zinc Issa-Madongo, Mathurin Mu, Ying Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title eth­yl–zinc complex, [Zn(C(2)H(5))(C(19)H(24)N(3))], bears a tridentate anilinide–aldimine ligand and features one long Zn—N(amine) bond length, attributable to the crowded environment of the coordinated metal, arising from the dimethyl­phenyl group. The Zn(II) ion adopts a distorted tetra­hedral geometry, the dihedral angle between the two benzene rings being 86.05 (16)°. International Union of Crystallography 2011-02-23 /pmc/articles/PMC3052042/ /pubmed/21522288 http://dx.doi.org/10.1107/S1600536811005514 Text en © Issa-Madongo and Mu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Issa-Madongo, Mathurin
Mu, Ying
[N-((E)-2-{[2-(Dimethyl­amino)­eth­yl]imino­meth­yl}phen­yl)-N-(2,6-dimethyl­phen­yl)anilinido-κ(3) N,N′,N′′]ethyl­zinc
title [N-((E)-2-{[2-(Dimethyl­amino)­eth­yl]imino­meth­yl}phen­yl)-N-(2,6-dimethyl­phen­yl)anilinido-κ(3) N,N′,N′′]ethyl­zinc
title_full [N-((E)-2-{[2-(Dimethyl­amino)­eth­yl]imino­meth­yl}phen­yl)-N-(2,6-dimethyl­phen­yl)anilinido-κ(3) N,N′,N′′]ethyl­zinc
title_fullStr [N-((E)-2-{[2-(Dimethyl­amino)­eth­yl]imino­meth­yl}phen­yl)-N-(2,6-dimethyl­phen­yl)anilinido-κ(3) N,N′,N′′]ethyl­zinc
title_full_unstemmed [N-((E)-2-{[2-(Dimethyl­amino)­eth­yl]imino­meth­yl}phen­yl)-N-(2,6-dimethyl­phen­yl)anilinido-κ(3) N,N′,N′′]ethyl­zinc
title_short [N-((E)-2-{[2-(Dimethyl­amino)­eth­yl]imino­meth­yl}phen­yl)-N-(2,6-dimethyl­phen­yl)anilinido-κ(3) N,N′,N′′]ethyl­zinc
title_sort [n-((e)-2-{[2-(dimethyl­amino)­eth­yl]imino­meth­yl}phen­yl)-n-(2,6-dimethyl­phen­yl)anilinido-κ(3) n,n′,n′′]ethyl­zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052042/
https://www.ncbi.nlm.nih.gov/pubmed/21522288
http://dx.doi.org/10.1107/S1600536811005514
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AT muying ne22dimethylaminoethyliminomethylphenyln26dimethylphenylanilinidok3nnnethylzinc

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