Bis(μ-N-nitroso-N-phenyl­hydroxy­laminato)-κ(3) O,O′:O′;κ(3) O′:O,O′-bis­[(N-nitroso-N-phenyl­hydroxy­laminato-κ(2) O,O′)lead(II)]

The four cupferronate ions in the dinuclear title compound, [Pb(2)(C(6)H(5)N(2)O(2))(4)], O,O′-chelate to the two Pb(II) atoms; two of the four nitroso O atoms are also involved in bridging. The geometry of both five-coordinate Pb(II)atoms is distorted Ψ-octa­hedral; if another two longer inter­mole...

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Detalles Bibliográficos
Autores principales: Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052047/
https://www.ncbi.nlm.nih.gov/pubmed/21522298
http://dx.doi.org/10.1107/S1600536811006775
Descripción
Sumario:The four cupferronate ions in the dinuclear title compound, [Pb(2)(C(6)H(5)N(2)O(2))(4)], O,O′-chelate to the two Pb(II) atoms; two of the four nitroso O atoms are also involved in bridging. The geometry of both five-coordinate Pb(II)atoms is distorted Ψ-octa­hedral; if another two longer inter­molecular Pb⋯O inter­actions [at 2.955 (1) and 3.099 (1) Å] are considered, the geometry is a distorted Ψ-square anti­prism.

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