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Bis(μ-N-nitroso-N-phenylhydroxylaminato)-κ(3) O,O′:O′;κ(3) O′:O,O′-bis[(N-nitroso-N-phenylhydroxylaminato-κ(2) O,O′)lead(II)]
The four cupferronate ions in the dinuclear title compound, [Pb(2)(C(6)H(5)N(2)O(2))(4)], O,O′-chelate to the two Pb(II) atoms; two of the four nitroso O atoms are also involved in bridging. The geometry of both five-coordinate Pb(II)atoms is distorted Ψ-octahedral; if another two longer intermole...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052047/ https://www.ncbi.nlm.nih.gov/pubmed/21522298 http://dx.doi.org/10.1107/S1600536811006775 |
| _version_ | 1782199614714150912 |
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| author | Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng |
| author_facet | Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng |
| author_sort | Najafi, Ezzatollah |
| collection | PubMed |
| description | The four cupferronate ions in the dinuclear title compound, [Pb(2)(C(6)H(5)N(2)O(2))(4)], O,O′-chelate to the two Pb(II) atoms; two of the four nitroso O atoms are also involved in bridging. The geometry of both five-coordinate Pb(II)atoms is distorted Ψ-octahedral; if another two longer intermolecular Pb⋯O interactions [at 2.955 (1) and 3.099 (1) Å] are considered, the geometry is a distorted Ψ-square antiprism. |
| format | Text |
| id | pubmed-3052047 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30520472011-04-26 Bis(μ-N-nitroso-N-phenylhydroxylaminato)-κ(3) O,O′:O′;κ(3) O′:O,O′-bis[(N-nitroso-N-phenylhydroxylaminato-κ(2) O,O′)lead(II)] Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The four cupferronate ions in the dinuclear title compound, [Pb(2)(C(6)H(5)N(2)O(2))(4)], O,O′-chelate to the two Pb(II) atoms; two of the four nitroso O atoms are also involved in bridging. The geometry of both five-coordinate Pb(II)atoms is distorted Ψ-octahedral; if another two longer intermolecular Pb⋯O interactions [at 2.955 (1) and 3.099 (1) Å] are considered, the geometry is a distorted Ψ-square antiprism. International Union of Crystallography 2011-02-26 /pmc/articles/PMC3052047/ /pubmed/21522298 http://dx.doi.org/10.1107/S1600536811006775 Text en © Najafi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Bis(μ-N-nitroso-N-phenylhydroxylaminato)-κ(3) O,O′:O′;κ(3) O′:O,O′-bis[(N-nitroso-N-phenylhydroxylaminato-κ(2) O,O′)lead(II)] |
| title | Bis(μ-N-nitroso-N-phenylhydroxylaminato)-κ(3)
O,O′:O′;κ(3)
O′:O,O′-bis[(N-nitroso-N-phenylhydroxylaminato-κ(2)
O,O′)lead(II)] |
| title_full | Bis(μ-N-nitroso-N-phenylhydroxylaminato)-κ(3)
O,O′:O′;κ(3)
O′:O,O′-bis[(N-nitroso-N-phenylhydroxylaminato-κ(2)
O,O′)lead(II)] |
| title_fullStr | Bis(μ-N-nitroso-N-phenylhydroxylaminato)-κ(3)
O,O′:O′;κ(3)
O′:O,O′-bis[(N-nitroso-N-phenylhydroxylaminato-κ(2)
O,O′)lead(II)] |
| title_full_unstemmed | Bis(μ-N-nitroso-N-phenylhydroxylaminato)-κ(3)
O,O′:O′;κ(3)
O′:O,O′-bis[(N-nitroso-N-phenylhydroxylaminato-κ(2)
O,O′)lead(II)] |
| title_short | Bis(μ-N-nitroso-N-phenylhydroxylaminato)-κ(3)
O,O′:O′;κ(3)
O′:O,O′-bis[(N-nitroso-N-phenylhydroxylaminato-κ(2)
O,O′)lead(II)] |
| title_sort | bis(μ-n-nitroso-n-phenylhydroxylaminato)-κ(3)
o,o′:o′;κ(3)
o′:o,o′-bis[(n-nitroso-n-phenylhydroxylaminato-κ(2)
o,o′)lead(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052047/ https://www.ncbi.nlm.nih.gov/pubmed/21522298 http://dx.doi.org/10.1107/S1600536811006775 |
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