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Poly[diaquatris(μ(4)-1,3-phenylenediacetato)dicerium(III)]
In the title coordination polymer, [Ce(2)(C(10)H(8)O(4))(3)(H(2)O)(2)](n), each Ce(III) atom is nine-coordinated by eight O atoms from six different 1,3-phenylenediacetate (pda) bivalent anions and one O atom from a coordinated water molecule, forming a distorted tricapped trigonal–prismatic coord...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052048/ https://www.ncbi.nlm.nih.gov/pubmed/21522246 http://dx.doi.org/10.1107/S1600536811003801 |
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author | Gao, Zhu-Qing Li, Hong-Jin Gu, Jin-Zhong |
author_facet | Gao, Zhu-Qing Li, Hong-Jin Gu, Jin-Zhong |
author_sort | Gao, Zhu-Qing |
collection | PubMed |
description | In the title coordination polymer, [Ce(2)(C(10)H(8)O(4))(3)(H(2)O)(2)](n), each Ce(III) atom is nine-coordinated by eight O atoms from six different 1,3-phenylenediacetate (pda) bivalent anions and one O atom from a coordinated water molecule, forming a distorted tricapped trigonal–prismatic coordination geometry. Eight Ce(III) ions and twelve pda ligands form a large [Ce(8)(pda)(12)] ring, and four Ce(III) ions and six pda ligands form a small [Ce(4)(pda)(6)] ring. The rings are further connected by the coordination interactions of pda ligands and Ce(III), generating a three-dimensional supramolecular framework. |
format | Text |
id | pubmed-3052048 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30520482011-04-26 Poly[diaquatris(μ(4)-1,3-phenylenediacetato)dicerium(III)] Gao, Zhu-Qing Li, Hong-Jin Gu, Jin-Zhong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Ce(2)(C(10)H(8)O(4))(3)(H(2)O)(2)](n), each Ce(III) atom is nine-coordinated by eight O atoms from six different 1,3-phenylenediacetate (pda) bivalent anions and one O atom from a coordinated water molecule, forming a distorted tricapped trigonal–prismatic coordination geometry. Eight Ce(III) ions and twelve pda ligands form a large [Ce(8)(pda)(12)] ring, and four Ce(III) ions and six pda ligands form a small [Ce(4)(pda)(6)] ring. The rings are further connected by the coordination interactions of pda ligands and Ce(III), generating a three-dimensional supramolecular framework. International Union of Crystallography 2011-02-09 /pmc/articles/PMC3052048/ /pubmed/21522246 http://dx.doi.org/10.1107/S1600536811003801 Text en © Gao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gao, Zhu-Qing Li, Hong-Jin Gu, Jin-Zhong Poly[diaquatris(μ(4)-1,3-phenylenediacetato)dicerium(III)] |
title | Poly[diaquatris(μ(4)-1,3-phenylenediacetato)dicerium(III)] |
title_full | Poly[diaquatris(μ(4)-1,3-phenylenediacetato)dicerium(III)] |
title_fullStr | Poly[diaquatris(μ(4)-1,3-phenylenediacetato)dicerium(III)] |
title_full_unstemmed | Poly[diaquatris(μ(4)-1,3-phenylenediacetato)dicerium(III)] |
title_short | Poly[diaquatris(μ(4)-1,3-phenylenediacetato)dicerium(III)] |
title_sort | poly[diaquatris(μ(4)-1,3-phenylenediacetato)dicerium(iii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052048/ https://www.ncbi.nlm.nih.gov/pubmed/21522246 http://dx.doi.org/10.1107/S1600536811003801 |
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