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4,4′-Bipyridine–5-fluoroisophthalic acid (1/1)
Co-crystallization of 5-fluoroisophthalic acid (H(2)fip) with 4,4′-bipyridine (bipy) leads to the formation of the title compound [(H(2)fip)(bipy)], C(8)H(5)FO(4)·C(10)H(8)N(2), with an acid–base molar ratio of 1:1. The acid and base subunits are arrange alternately in the crystal structure, displa...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052053/ https://www.ncbi.nlm.nih.gov/pubmed/21522350 http://dx.doi.org/10.1107/S1600536811004016 |
| _version_ | 1782199616150700032 |
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| author | Qin, Jin-Lai |
| author_facet | Qin, Jin-Lai |
| author_sort | Qin, Jin-Lai |
| collection | PubMed |
| description | Co-crystallization of 5-fluoroisophthalic acid (H(2)fip) with 4,4′-bipyridine (bipy) leads to the formation of the title compound [(H(2)fip)(bipy)], C(8)H(5)FO(4)·C(10)H(8)N(2), with an acid–base molar ratio of 1:1. The acid and base subunits are arrange alternately in the crystal structure, displaying a wave-like tape motif via intermolecular O—H⋯N and C—H⋯O hydrogen bonds [carboxyl–pyridine synthon of R (2) (2)(7) hydrogen-bond notation], which are further combined into a two-dimensional architecture through C—H⋯F interactions involving the bipy and H(2)fip molecules. |
| format | Text |
| id | pubmed-3052053 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30520532011-04-26 4,4′-Bipyridine–5-fluoroisophthalic acid (1/1) Qin, Jin-Lai Acta Crystallogr Sect E Struct Rep Online Organic Papers Co-crystallization of 5-fluoroisophthalic acid (H(2)fip) with 4,4′-bipyridine (bipy) leads to the formation of the title compound [(H(2)fip)(bipy)], C(8)H(5)FO(4)·C(10)H(8)N(2), with an acid–base molar ratio of 1:1. The acid and base subunits are arrange alternately in the crystal structure, displaying a wave-like tape motif via intermolecular O—H⋯N and C—H⋯O hydrogen bonds [carboxyl–pyridine synthon of R (2) (2)(7) hydrogen-bond notation], which are further combined into a two-dimensional architecture through C—H⋯F interactions involving the bipy and H(2)fip molecules. International Union of Crystallography 2011-02-09 /pmc/articles/PMC3052053/ /pubmed/21522350 http://dx.doi.org/10.1107/S1600536811004016 Text en © Jin-Lai Qin 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Qin, Jin-Lai 4,4′-Bipyridine–5-fluoroisophthalic acid (1/1) |
| title | 4,4′-Bipyridine–5-fluoroisophthalic acid (1/1) |
| title_full | 4,4′-Bipyridine–5-fluoroisophthalic acid (1/1) |
| title_fullStr | 4,4′-Bipyridine–5-fluoroisophthalic acid (1/1) |
| title_full_unstemmed | 4,4′-Bipyridine–5-fluoroisophthalic acid (1/1) |
| title_short | 4,4′-Bipyridine–5-fluoroisophthalic acid (1/1) |
| title_sort | 4,4′-bipyridine–5-fluoroisophthalic acid (1/1) |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052053/ https://www.ncbi.nlm.nih.gov/pubmed/21522350 http://dx.doi.org/10.1107/S1600536811004016 |
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