4-Amino-3-methyl­benzoic acid–1,2-bis­(4-pyrid­yl)ethane (1/1)

In the crystal structure of the title 1:1 adduct, C(12)H(12)N(2)·C(8)H(9)NO(2), the 4-amino-3-methyl­benzoic acid mol­ecules and 1,2-bis­(4-pyrid­yl)ethane mol­ecules are linked by inter­molecular O—H⋯N, N—H⋯O and N—H⋯N hydrogen bonds, forming a two-dimensional supra­molecular network parallel to (0...

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Detalles Bibliográficos
Autores principales: Lush, Shie Fu, Chen, Chong Wei, Yang, Chieh, Shen, Fwu Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052056/
https://www.ncbi.nlm.nih.gov/pubmed/21522404
http://dx.doi.org/10.1107/S1600536811005381
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author Lush, Shie Fu
Chen, Chong Wei
Yang, Chieh
Shen, Fwu Ming
author_facet Lush, Shie Fu
Chen, Chong Wei
Yang, Chieh
Shen, Fwu Ming
author_sort Lush, Shie Fu
collection PubMed
description In the crystal structure of the title 1:1 adduct, C(12)H(12)N(2)·C(8)H(9)NO(2), the 4-amino-3-methyl­benzoic acid mol­ecules and 1,2-bis­(4-pyrid­yl)ethane mol­ecules are linked by inter­molecular O—H⋯N, N—H⋯O and N—H⋯N hydrogen bonds, forming a two-dimensional supra­molecular network parallel to (001). In the 1,2-bis­(4-pyrid­yl)ethane mol­ecule, the two pyridine rings are twisted to each other by a dihedral angle of 12.12 (8)°. The non-H atoms of the 4-amino-3-methyl­benzoic acid mol­ecule are almost coplanar, the maximum atomic deviation being 0.029 (1) Å. Weak C—H⋯π inter­actions are present in the crystal structure.
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spelling pubmed-30520562011-04-26 4-Amino-3-methyl­benzoic acid–1,2-bis­(4-pyrid­yl)ethane (1/1) Lush, Shie Fu Chen, Chong Wei Yang, Chieh Shen, Fwu Ming Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title 1:1 adduct, C(12)H(12)N(2)·C(8)H(9)NO(2), the 4-amino-3-methyl­benzoic acid mol­ecules and 1,2-bis­(4-pyrid­yl)ethane mol­ecules are linked by inter­molecular O—H⋯N, N—H⋯O and N—H⋯N hydrogen bonds, forming a two-dimensional supra­molecular network parallel to (001). In the 1,2-bis­(4-pyrid­yl)ethane mol­ecule, the two pyridine rings are twisted to each other by a dihedral angle of 12.12 (8)°. The non-H atoms of the 4-amino-3-methyl­benzoic acid mol­ecule are almost coplanar, the maximum atomic deviation being 0.029 (1) Å. Weak C—H⋯π inter­actions are present in the crystal structure. International Union of Crystallography 2011-02-19 /pmc/articles/PMC3052056/ /pubmed/21522404 http://dx.doi.org/10.1107/S1600536811005381 Text en © Lush et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lush, Shie Fu
Chen, Chong Wei
Yang, Chieh
Shen, Fwu Ming
4-Amino-3-methyl­benzoic acid–1,2-bis­(4-pyrid­yl)ethane (1/1)
title 4-Amino-3-methyl­benzoic acid–1,2-bis­(4-pyrid­yl)ethane (1/1)
title_full 4-Amino-3-methyl­benzoic acid–1,2-bis­(4-pyrid­yl)ethane (1/1)
title_fullStr 4-Amino-3-methyl­benzoic acid–1,2-bis­(4-pyrid­yl)ethane (1/1)
title_full_unstemmed 4-Amino-3-methyl­benzoic acid–1,2-bis­(4-pyrid­yl)ethane (1/1)
title_short 4-Amino-3-methyl­benzoic acid–1,2-bis­(4-pyrid­yl)ethane (1/1)
title_sort 4-amino-3-methyl­benzoic acid–1,2-bis­(4-pyrid­yl)ethane (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052056/
https://www.ncbi.nlm.nih.gov/pubmed/21522404
http://dx.doi.org/10.1107/S1600536811005381
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