[(1R*,2S*)-N (1)-Benzyl-2-phenyl-1-(pyridin-2-yl)-N (2)-(pyridin-2-ylmeth­yl)ethane-1,2-diamine]­dichloridozinc(II)

In the mononuclear zinc title complex, [ZnCl(2)(C(26)H(26)N(4))], the Zn(II) ion is surrounded by three N atoms from a (1R*,2S*)-N (1)-benzyl-2-phenyl-1-(pyridin-2-yl)-N (2)-(pyridin-2-ylmeth­yl)ethane-1,2-diamine (BPPPEN) ligand and two terminal chloride ligands, resulting in a highly distorted env...

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Detalles Bibliográficos
Autores principales: Bortoluzzi, Adailton J., Mireski, Sandro L., Joussef, Antonio C.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052059/
https://www.ncbi.nlm.nih.gov/pubmed/21522267
http://dx.doi.org/10.1107/S1600536811004314
Descripción
Sumario:In the mononuclear zinc title complex, [ZnCl(2)(C(26)H(26)N(4))], the Zn(II) ion is surrounded by three N atoms from a (1R*,2S*)-N (1)-benzyl-2-phenyl-1-(pyridin-2-yl)-N (2)-(pyridin-2-ylmeth­yl)ethane-1,2-diamine (BPPPEN) ligand and two terminal chloride ligands, resulting in a highly distorted environment around the metal atom. The calculated τ parameter of 0.42 indicates that the coordination geometry is approximately square-pyramidal. Hydrogen bonds involving centrosymmetric N—H⋯Cl inter­actions form dimeric structures. The mol­ecules are stacked along the a and b axes.

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