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[(1R*,2S*)-N (1)-Benzyl-2-phenyl-1-(pyridin-2-yl)-N (2)-(pyridin-2-ylmethyl)ethane-1,2-diamine]dichloridozinc(II)
In the mononuclear zinc title complex, [ZnCl(2)(C(26)H(26)N(4))], the Zn(II) ion is surrounded by three N atoms from a (1R*,2S*)-N (1)-benzyl-2-phenyl-1-(pyridin-2-yl)-N (2)-(pyridin-2-ylmethyl)ethane-1,2-diamine (BPPPEN) ligand and two terminal chloride ligands, resulting in a highly distorted env...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052059/ https://www.ncbi.nlm.nih.gov/pubmed/21522267 http://dx.doi.org/10.1107/S1600536811004314 |
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author | Bortoluzzi, Adailton J. Mireski, Sandro L. Joussef, Antonio C. |
author_facet | Bortoluzzi, Adailton J. Mireski, Sandro L. Joussef, Antonio C. |
author_sort | Bortoluzzi, Adailton J. |
collection | PubMed |
description | In the mononuclear zinc title complex, [ZnCl(2)(C(26)H(26)N(4))], the Zn(II) ion is surrounded by three N atoms from a (1R*,2S*)-N (1)-benzyl-2-phenyl-1-(pyridin-2-yl)-N (2)-(pyridin-2-ylmethyl)ethane-1,2-diamine (BPPPEN) ligand and two terminal chloride ligands, resulting in a highly distorted environment around the metal atom. The calculated τ parameter of 0.42 indicates that the coordination geometry is approximately square-pyramidal. Hydrogen bonds involving centrosymmetric N—H⋯Cl interactions form dimeric structures. The molecules are stacked along the a and b axes. |
format | Text |
id | pubmed-3052059 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30520592011-04-26 [(1R*,2S*)-N (1)-Benzyl-2-phenyl-1-(pyridin-2-yl)-N (2)-(pyridin-2-ylmethyl)ethane-1,2-diamine]dichloridozinc(II) Bortoluzzi, Adailton J. Mireski, Sandro L. Joussef, Antonio C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear zinc title complex, [ZnCl(2)(C(26)H(26)N(4))], the Zn(II) ion is surrounded by three N atoms from a (1R*,2S*)-N (1)-benzyl-2-phenyl-1-(pyridin-2-yl)-N (2)-(pyridin-2-ylmethyl)ethane-1,2-diamine (BPPPEN) ligand and two terminal chloride ligands, resulting in a highly distorted environment around the metal atom. The calculated τ parameter of 0.42 indicates that the coordination geometry is approximately square-pyramidal. Hydrogen bonds involving centrosymmetric N—H⋯Cl interactions form dimeric structures. The molecules are stacked along the a and b axes. International Union of Crystallography 2011-02-16 /pmc/articles/PMC3052059/ /pubmed/21522267 http://dx.doi.org/10.1107/S1600536811004314 Text en © Bortoluzzi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bortoluzzi, Adailton J. Mireski, Sandro L. Joussef, Antonio C. [(1R*,2S*)-N (1)-Benzyl-2-phenyl-1-(pyridin-2-yl)-N (2)-(pyridin-2-ylmethyl)ethane-1,2-diamine]dichloridozinc(II) |
title | [(1R*,2S*)-N
(1)-Benzyl-2-phenyl-1-(pyridin-2-yl)-N
(2)-(pyridin-2-ylmethyl)ethane-1,2-diamine]dichloridozinc(II) |
title_full | [(1R*,2S*)-N
(1)-Benzyl-2-phenyl-1-(pyridin-2-yl)-N
(2)-(pyridin-2-ylmethyl)ethane-1,2-diamine]dichloridozinc(II) |
title_fullStr | [(1R*,2S*)-N
(1)-Benzyl-2-phenyl-1-(pyridin-2-yl)-N
(2)-(pyridin-2-ylmethyl)ethane-1,2-diamine]dichloridozinc(II) |
title_full_unstemmed | [(1R*,2S*)-N
(1)-Benzyl-2-phenyl-1-(pyridin-2-yl)-N
(2)-(pyridin-2-ylmethyl)ethane-1,2-diamine]dichloridozinc(II) |
title_short | [(1R*,2S*)-N
(1)-Benzyl-2-phenyl-1-(pyridin-2-yl)-N
(2)-(pyridin-2-ylmethyl)ethane-1,2-diamine]dichloridozinc(II) |
title_sort | [(1r*,2s*)-n
(1)-benzyl-2-phenyl-1-(pyridin-2-yl)-n
(2)-(pyridin-2-ylmethyl)ethane-1,2-diamine]dichloridozinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052059/ https://www.ncbi.nlm.nih.gov/pubmed/21522267 http://dx.doi.org/10.1107/S1600536811004314 |
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