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[(1R*,2S*)-N (1)-Benzyl-2-phenyl-1-(pyridin-2-yl)-N (2)-(pyridin-2-ylmeth­yl)ethane-1,2-diamine]­dichloridozinc(II)

In the mononuclear zinc title complex, [ZnCl(2)(C(26)H(26)N(4))], the Zn(II) ion is surrounded by three N atoms from a (1R*,2S*)-N (1)-benzyl-2-phenyl-1-(pyridin-2-yl)-N (2)-(pyridin-2-ylmeth­yl)ethane-1,2-diamine (BPPPEN) ligand and two terminal chloride ligands, resulting in a highly distorted env...

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Detalles Bibliográficos
Autores principales: Bortoluzzi, Adailton J., Mireski, Sandro L., Joussef, Antonio C.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052059/
https://www.ncbi.nlm.nih.gov/pubmed/21522267
http://dx.doi.org/10.1107/S1600536811004314
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author Bortoluzzi, Adailton J.
Mireski, Sandro L.
Joussef, Antonio C.
author_facet Bortoluzzi, Adailton J.
Mireski, Sandro L.
Joussef, Antonio C.
author_sort Bortoluzzi, Adailton J.
collection PubMed
description In the mononuclear zinc title complex, [ZnCl(2)(C(26)H(26)N(4))], the Zn(II) ion is surrounded by three N atoms from a (1R*,2S*)-N (1)-benzyl-2-phenyl-1-(pyridin-2-yl)-N (2)-(pyridin-2-ylmeth­yl)ethane-1,2-diamine (BPPPEN) ligand and two terminal chloride ligands, resulting in a highly distorted environment around the metal atom. The calculated τ parameter of 0.42 indicates that the coordination geometry is approximately square-pyramidal. Hydrogen bonds involving centrosymmetric N—H⋯Cl inter­actions form dimeric structures. The mol­ecules are stacked along the a and b axes.
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spelling pubmed-30520592011-04-26 [(1R*,2S*)-N (1)-Benzyl-2-phenyl-1-(pyridin-2-yl)-N (2)-(pyridin-2-ylmeth­yl)ethane-1,2-diamine]­dichloridozinc(II) Bortoluzzi, Adailton J. Mireski, Sandro L. Joussef, Antonio C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear zinc title complex, [ZnCl(2)(C(26)H(26)N(4))], the Zn(II) ion is surrounded by three N atoms from a (1R*,2S*)-N (1)-benzyl-2-phenyl-1-(pyridin-2-yl)-N (2)-(pyridin-2-ylmeth­yl)ethane-1,2-diamine (BPPPEN) ligand and two terminal chloride ligands, resulting in a highly distorted environment around the metal atom. The calculated τ parameter of 0.42 indicates that the coordination geometry is approximately square-pyramidal. Hydrogen bonds involving centrosymmetric N—H⋯Cl inter­actions form dimeric structures. The mol­ecules are stacked along the a and b axes. International Union of Crystallography 2011-02-16 /pmc/articles/PMC3052059/ /pubmed/21522267 http://dx.doi.org/10.1107/S1600536811004314 Text en © Bortoluzzi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bortoluzzi, Adailton J.
Mireski, Sandro L.
Joussef, Antonio C.
[(1R*,2S*)-N (1)-Benzyl-2-phenyl-1-(pyridin-2-yl)-N (2)-(pyridin-2-ylmeth­yl)ethane-1,2-diamine]­dichloridozinc(II)
title [(1R*,2S*)-N (1)-Benzyl-2-phenyl-1-(pyridin-2-yl)-N (2)-(pyridin-2-ylmeth­yl)ethane-1,2-diamine]­dichloridozinc(II)
title_full [(1R*,2S*)-N (1)-Benzyl-2-phenyl-1-(pyridin-2-yl)-N (2)-(pyridin-2-ylmeth­yl)ethane-1,2-diamine]­dichloridozinc(II)
title_fullStr [(1R*,2S*)-N (1)-Benzyl-2-phenyl-1-(pyridin-2-yl)-N (2)-(pyridin-2-ylmeth­yl)ethane-1,2-diamine]­dichloridozinc(II)
title_full_unstemmed [(1R*,2S*)-N (1)-Benzyl-2-phenyl-1-(pyridin-2-yl)-N (2)-(pyridin-2-ylmeth­yl)ethane-1,2-diamine]­dichloridozinc(II)
title_short [(1R*,2S*)-N (1)-Benzyl-2-phenyl-1-(pyridin-2-yl)-N (2)-(pyridin-2-ylmeth­yl)ethane-1,2-diamine]­dichloridozinc(II)
title_sort [(1r*,2s*)-n (1)-benzyl-2-phenyl-1-(pyridin-2-yl)-n (2)-(pyridin-2-ylmeth­yl)ethane-1,2-diamine]­dichloridozinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052059/
https://www.ncbi.nlm.nih.gov/pubmed/21522267
http://dx.doi.org/10.1107/S1600536811004314
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