5,7,7,12,14,14-Hexamethyl-4,8-diaza-1,11-diazo­niocyclotetra­deca-4,11-diene diiodide dihydrate

The asymmetric unit of the title compound, C(16)H(34)N(4) (2+)·2I(−)·2H(2)O, contains one half-cation, one iodide anion and one water mol­ecule. The cation has crystallographically imposed centrosymmetric symmetry. Despite some differences in the unit-cell dimensions, packing analysis on a cluster o...

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Detalles Bibliográficos
Autores principales: Kennedy, Alan R., Lutta, Samwel T., Morrison, Catriona A., Okoth, Maurice O., Orang’o, Daniel M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052064/
https://www.ncbi.nlm.nih.gov/pubmed/21522429
http://dx.doi.org/10.1107/S1600536811005848
Descripción
Sumario:The asymmetric unit of the title compound, C(16)H(34)N(4) (2+)·2I(−)·2H(2)O, contains one half-cation, one iodide anion and one water mol­ecule. The cation has crystallographically imposed centrosymmetric symmetry. Despite some differences in the unit-cell dimensions, packing analysis on a cluster of 15 cations and a comparison of the hydrogen bonding suggests that this compound is isostructural with its bromide analogue. Inter­molecular hydrogen bonding forms eight-membered [H—O—H⋯I](2) and [H—N—H⋯I](2) rings and creates a sheet structure.

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