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5,7,7,12,14,14-Hexamethyl-4,8-diaza-1,11-diazoniocyclotetradeca-4,11-diene diiodide dihydrate
The asymmetric unit of the title compound, C(16)H(34)N(4) (2+)·2I(−)·2H(2)O, contains one half-cation, one iodide anion and one water molecule. The cation has crystallographically imposed centrosymmetric symmetry. Despite some differences in the unit-cell dimensions, packing analysis on a cluster o...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052064/ https://www.ncbi.nlm.nih.gov/pubmed/21522429 http://dx.doi.org/10.1107/S1600536811005848 |
| _version_ | 1782199618786820096 |
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| author | Kennedy, Alan R. Lutta, Samwel T. Morrison, Catriona A. Okoth, Maurice O. Orang’o, Daniel M. |
| author_facet | Kennedy, Alan R. Lutta, Samwel T. Morrison, Catriona A. Okoth, Maurice O. Orang’o, Daniel M. |
| author_sort | Kennedy, Alan R. |
| collection | PubMed |
| description | The asymmetric unit of the title compound, C(16)H(34)N(4) (2+)·2I(−)·2H(2)O, contains one half-cation, one iodide anion and one water molecule. The cation has crystallographically imposed centrosymmetric symmetry. Despite some differences in the unit-cell dimensions, packing analysis on a cluster of 15 cations and a comparison of the hydrogen bonding suggests that this compound is isostructural with its bromide analogue. Intermolecular hydrogen bonding forms eight-membered [H—O—H⋯I](2) and [H—N—H⋯I](2) rings and creates a sheet structure. |
| format | Text |
| id | pubmed-3052064 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30520642011-04-26 5,7,7,12,14,14-Hexamethyl-4,8-diaza-1,11-diazoniocyclotetradeca-4,11-diene diiodide dihydrate Kennedy, Alan R. Lutta, Samwel T. Morrison, Catriona A. Okoth, Maurice O. Orang’o, Daniel M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(16)H(34)N(4) (2+)·2I(−)·2H(2)O, contains one half-cation, one iodide anion and one water molecule. The cation has crystallographically imposed centrosymmetric symmetry. Despite some differences in the unit-cell dimensions, packing analysis on a cluster of 15 cations and a comparison of the hydrogen bonding suggests that this compound is isostructural with its bromide analogue. Intermolecular hydrogen bonding forms eight-membered [H—O—H⋯I](2) and [H—N—H⋯I](2) rings and creates a sheet structure. International Union of Crystallography 2011-02-23 /pmc/articles/PMC3052064/ /pubmed/21522429 http://dx.doi.org/10.1107/S1600536811005848 Text en © Kennedy et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Kennedy, Alan R. Lutta, Samwel T. Morrison, Catriona A. Okoth, Maurice O. Orang’o, Daniel M. 5,7,7,12,14,14-Hexamethyl-4,8-diaza-1,11-diazoniocyclotetradeca-4,11-diene diiodide dihydrate |
| title | 5,7,7,12,14,14-Hexamethyl-4,8-diaza-1,11-diazoniocyclotetradeca-4,11-diene diiodide dihydrate |
| title_full | 5,7,7,12,14,14-Hexamethyl-4,8-diaza-1,11-diazoniocyclotetradeca-4,11-diene diiodide dihydrate |
| title_fullStr | 5,7,7,12,14,14-Hexamethyl-4,8-diaza-1,11-diazoniocyclotetradeca-4,11-diene diiodide dihydrate |
| title_full_unstemmed | 5,7,7,12,14,14-Hexamethyl-4,8-diaza-1,11-diazoniocyclotetradeca-4,11-diene diiodide dihydrate |
| title_short | 5,7,7,12,14,14-Hexamethyl-4,8-diaza-1,11-diazoniocyclotetradeca-4,11-diene diiodide dihydrate |
| title_sort | 5,7,7,12,14,14-hexamethyl-4,8-diaza-1,11-diazoniocyclotetradeca-4,11-diene diiodide dihydrate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052064/ https://www.ncbi.nlm.nih.gov/pubmed/21522429 http://dx.doi.org/10.1107/S1600536811005848 |
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