2,5-Dimethyl-3-[4-(trifluoro­meth­oxy)anilino]­cyclo­hex-2-enone

In the title compound, C(15)H(16)F(3)NO(2), the dihedral angle between the benzene ring and the conjugated part of the cyclo­hexene ring is 60.00 (8)°. The non-conjugated part of the cyclohexene ring and the trifluoro­methyl group are both disordered over two sets of sites with occupancies of 0.835 ...

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Autores principales: North, Henry, Wutoh, Kwame, Odoom, M’egya K., Karla, Pradeep, Scott, Kenneth R., Butcher, Ray J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052066/
https://www.ncbi.nlm.nih.gov/pubmed/21522361
http://dx.doi.org/10.1107/S1600536811004338
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author North, Henry
Wutoh, Kwame
Odoom, M’egya K.
Karla, Pradeep
Scott, Kenneth R.
Butcher, Ray J.
author_facet North, Henry
Wutoh, Kwame
Odoom, M’egya K.
Karla, Pradeep
Scott, Kenneth R.
Butcher, Ray J.
author_sort North, Henry
collection PubMed
description In the title compound, C(15)H(16)F(3)NO(2), the dihedral angle between the benzene ring and the conjugated part of the cyclo­hexene ring is 60.00 (8)°. The non-conjugated part of the cyclohexene ring and the trifluoro­methyl group are both disordered over two sets of sites with occupancies of 0.835 (2) and 0.165 (2). In the crystal, mol­ecules are linked into chains along [010] by inter­molecular N—H⋯O hydrogen bonds. Weak inter­molecular C—H⋯O inter­actions also occur.
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spelling pubmed-30520662011-04-26 2,5-Dimethyl-3-[4-(trifluoro­meth­oxy)anilino]­cyclo­hex-2-enone North, Henry Wutoh, Kwame Odoom, M’egya K. Karla, Pradeep Scott, Kenneth R. Butcher, Ray J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(16)F(3)NO(2), the dihedral angle between the benzene ring and the conjugated part of the cyclo­hexene ring is 60.00 (8)°. The non-conjugated part of the cyclohexene ring and the trifluoro­methyl group are both disordered over two sets of sites with occupancies of 0.835 (2) and 0.165 (2). In the crystal, mol­ecules are linked into chains along [010] by inter­molecular N—H⋯O hydrogen bonds. Weak inter­molecular C—H⋯O inter­actions also occur. International Union of Crystallography 2011-02-12 /pmc/articles/PMC3052066/ /pubmed/21522361 http://dx.doi.org/10.1107/S1600536811004338 Text en © North et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
North, Henry
Wutoh, Kwame
Odoom, M’egya K.
Karla, Pradeep
Scott, Kenneth R.
Butcher, Ray J.
2,5-Dimethyl-3-[4-(trifluoro­meth­oxy)anilino]­cyclo­hex-2-enone
title 2,5-Dimethyl-3-[4-(trifluoro­meth­oxy)anilino]­cyclo­hex-2-enone
title_full 2,5-Dimethyl-3-[4-(trifluoro­meth­oxy)anilino]­cyclo­hex-2-enone
title_fullStr 2,5-Dimethyl-3-[4-(trifluoro­meth­oxy)anilino]­cyclo­hex-2-enone
title_full_unstemmed 2,5-Dimethyl-3-[4-(trifluoro­meth­oxy)anilino]­cyclo­hex-2-enone
title_short 2,5-Dimethyl-3-[4-(trifluoro­meth­oxy)anilino]­cyclo­hex-2-enone
title_sort 2,5-dimethyl-3-[4-(trifluoro­meth­oxy)anilino]­cyclo­hex-2-enone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052066/
https://www.ncbi.nlm.nih.gov/pubmed/21522361
http://dx.doi.org/10.1107/S1600536811004338
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