(E)-1-Methyl-5-(3-methyl-4-chloro­phen­oxy)-3-trifluoro­meth­yl-1H-pyrazole-4-carbaldehyde O-acetyl­oxime

In the title mol­ecule, C(15)H(13)ClF(3)N(3)O(3), the pyrazole and benzene rings form a dihedral angle of 77.6 (3)°. In the crystal, mol­ecules related by translation along the a axis are linked into chains via C—H⋯O hydrogen bonds. The crystal packing is stabilized further by weak π–π [centroid–cen...

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Detalles Bibliográficos
Autores principales: Dai, Hong, Shen, Yan-Fei, Chen, Jiao, Chen, Hong-Lian, Shen, Yong-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052068/
https://www.ncbi.nlm.nih.gov/pubmed/21522468
http://dx.doi.org/10.1107/S1600536811006696
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author Dai, Hong
Shen, Yan-Fei
Chen, Jiao
Chen, Hong-Lian
Shen, Yong-Jun
author_facet Dai, Hong
Shen, Yan-Fei
Chen, Jiao
Chen, Hong-Lian
Shen, Yong-Jun
author_sort Dai, Hong
collection PubMed
description In the title mol­ecule, C(15)H(13)ClF(3)N(3)O(3), the pyrazole and benzene rings form a dihedral angle of 77.6 (3)°. In the crystal, mol­ecules related by translation along the a axis are linked into chains via C—H⋯O hydrogen bonds. The crystal packing is stabilized further by weak π–π [centroid–centroid distance = 3.734 (6) Å] and dipole–dipole inter­actions [C⋯O = 3.174 (2) Å].
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spelling pubmed-30520682011-04-26 (E)-1-Methyl-5-(3-methyl-4-chloro­phen­oxy)-3-trifluoro­meth­yl-1H-pyrazole-4-carbaldehyde O-acetyl­oxime Dai, Hong Shen, Yan-Fei Chen, Jiao Chen, Hong-Lian Shen, Yong-Jun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(15)H(13)ClF(3)N(3)O(3), the pyrazole and benzene rings form a dihedral angle of 77.6 (3)°. In the crystal, mol­ecules related by translation along the a axis are linked into chains via C—H⋯O hydrogen bonds. The crystal packing is stabilized further by weak π–π [centroid–centroid distance = 3.734 (6) Å] and dipole–dipole inter­actions [C⋯O = 3.174 (2) Å]. International Union of Crystallography 2011-02-26 /pmc/articles/PMC3052068/ /pubmed/21522468 http://dx.doi.org/10.1107/S1600536811006696 Text en © Dai et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dai, Hong
Shen, Yan-Fei
Chen, Jiao
Chen, Hong-Lian
Shen, Yong-Jun
(E)-1-Methyl-5-(3-methyl-4-chloro­phen­oxy)-3-trifluoro­meth­yl-1H-pyrazole-4-carbaldehyde O-acetyl­oxime
title (E)-1-Methyl-5-(3-methyl-4-chloro­phen­oxy)-3-trifluoro­meth­yl-1H-pyrazole-4-carbaldehyde O-acetyl­oxime
title_full (E)-1-Methyl-5-(3-methyl-4-chloro­phen­oxy)-3-trifluoro­meth­yl-1H-pyrazole-4-carbaldehyde O-acetyl­oxime
title_fullStr (E)-1-Methyl-5-(3-methyl-4-chloro­phen­oxy)-3-trifluoro­meth­yl-1H-pyrazole-4-carbaldehyde O-acetyl­oxime
title_full_unstemmed (E)-1-Methyl-5-(3-methyl-4-chloro­phen­oxy)-3-trifluoro­meth­yl-1H-pyrazole-4-carbaldehyde O-acetyl­oxime
title_short (E)-1-Methyl-5-(3-methyl-4-chloro­phen­oxy)-3-trifluoro­meth­yl-1H-pyrazole-4-carbaldehyde O-acetyl­oxime
title_sort (e)-1-methyl-5-(3-methyl-4-chloro­phen­oxy)-3-trifluoro­meth­yl-1h-pyrazole-4-carbaldehyde o-acetyl­oxime
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052068/
https://www.ncbi.nlm.nih.gov/pubmed/21522468
http://dx.doi.org/10.1107/S1600536811006696
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