Bis(2-amino-5-chloro­pyridinium) tetra­chloridozincate

The asymmetric unit of the title compound, (C(5)H(6)ClN(2))(2)[ZnCl(4)], contains two 2-amino-5-chloro­pyridinium cations and one [ZnCl(4)](2−) dianion which are held together by N—H⋯Cl and C—H⋯Cl hydrogen bonds. The [ZnCl(4)](2−) anions have a distorted tetra­hedral geometry. Weak inter­molecular π...

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Detalles Bibliográficos
Autores principales: Kefi, Riadh, Jeanneau, Erwann, Lefebvre, Frederic, Ben Nasr, Cherif
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052069/
https://www.ncbi.nlm.nih.gov/pubmed/21522283
http://dx.doi.org/10.1107/S1600536811005691
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author Kefi, Riadh
Jeanneau, Erwann
Lefebvre, Frederic
Ben Nasr, Cherif
author_facet Kefi, Riadh
Jeanneau, Erwann
Lefebvre, Frederic
Ben Nasr, Cherif
author_sort Kefi, Riadh
collection PubMed
description The asymmetric unit of the title compound, (C(5)H(6)ClN(2))(2)[ZnCl(4)], contains two 2-amino-5-chloro­pyridinium cations and one [ZnCl(4)](2−) dianion which are held together by N—H⋯Cl and C—H⋯Cl hydrogen bonds. The [ZnCl(4)](2−) anions have a distorted tetra­hedral geometry. Weak inter­molecular π–π stacking inter­actions exist between neighbouring aromatic rings of the cations with a centroid–centroid distance of 3.712 (7) Å.
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spelling pubmed-30520692011-04-26 Bis(2-amino-5-chloro­pyridinium) tetra­chloridozincate Kefi, Riadh Jeanneau, Erwann Lefebvre, Frederic Ben Nasr, Cherif Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(5)H(6)ClN(2))(2)[ZnCl(4)], contains two 2-amino-5-chloro­pyridinium cations and one [ZnCl(4)](2−) dianion which are held together by N—H⋯Cl and C—H⋯Cl hydrogen bonds. The [ZnCl(4)](2−) anions have a distorted tetra­hedral geometry. Weak inter­molecular π–π stacking inter­actions exist between neighbouring aromatic rings of the cations with a centroid–centroid distance of 3.712 (7) Å. International Union of Crystallography 2011-02-23 /pmc/articles/PMC3052069/ /pubmed/21522283 http://dx.doi.org/10.1107/S1600536811005691 Text en © Kefi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kefi, Riadh
Jeanneau, Erwann
Lefebvre, Frederic
Ben Nasr, Cherif
Bis(2-amino-5-chloro­pyridinium) tetra­chloridozincate
title Bis(2-amino-5-chloro­pyridinium) tetra­chloridozincate
title_full Bis(2-amino-5-chloro­pyridinium) tetra­chloridozincate
title_fullStr Bis(2-amino-5-chloro­pyridinium) tetra­chloridozincate
title_full_unstemmed Bis(2-amino-5-chloro­pyridinium) tetra­chloridozincate
title_short Bis(2-amino-5-chloro­pyridinium) tetra­chloridozincate
title_sort bis(2-amino-5-chloro­pyridinium) tetra­chloridozincate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052069/
https://www.ncbi.nlm.nih.gov/pubmed/21522283
http://dx.doi.org/10.1107/S1600536811005691
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AT jeanneauerwann bis2amino5chloropyridiniumtetrachloridozincate
AT lefebvrefrederic bis2amino5chloropyridiniumtetrachloridozincate
AT bennasrcherif bis2amino5chloropyridiniumtetrachloridozincate

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