Cargando…

1-{5-[2-Chloro-5-(trifluoro­meth­yl)phen­yl]thio­phen-2-yl}ethanone

In the title molecule, C(13)H(8)ClF(3)OS, the dihedral angle between the mean planes of 2-chloro-5-(trifluoro­meth­yl)phenyl and tiophene rings is 54.37 (5)°. The acethyl group is twisted by 8.1 (2)° with respect to the thio­phene ring. The CF(3) group is disordered over two sets of sites with occup...

Descripción completa

Detalles Bibliográficos
Autores principales: Lytvyn, Roman, Horak, Yuri, Matiychuk, Vasyl, Obushak, Mykola, Kinzhybalo, Vasyl
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052071/
https://www.ncbi.nlm.nih.gov/pubmed/21522346
http://dx.doi.org/10.1107/S1600536811003965
Descripción
Sumario:In the title molecule, C(13)H(8)ClF(3)OS, the dihedral angle between the mean planes of 2-chloro-5-(trifluoro­meth­yl)phenyl and tiophene rings is 54.37 (5)°. The acethyl group is twisted by 8.1 (2)° with respect to the thio­phene ring. The CF(3) group is disordered over two sets of sites with occupations of 0.49 (3) and 0.51 (3). The crystal packing features C—H⋯F and C—H⋯O hydrogen bonds, forming dimers which are connected into chains along the c axis by C—H⋯O hydrogen bonds and C—Cl⋯π [Cl⋯π = 3.415 (1) Å and C—Cl⋯π = 151.56 (5)°] inter­actions. The chains are further connected into layers perpendicular to the a axis by C—H⋯O inter­actions.