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N,N′-Bis(2-methylphenyl)succinamide
In the title compound, C(18)H(20)N(2)O(2), the conformations of the N—H and C=O bonds in the C—NH—C(O)—C segments are anti to each other and the amide O atom is anti to the H atoms attached to the adjacent C atoms. Further, the conformations of the N—H bonds in the amide fragments are anti to the or...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052079/ https://www.ncbi.nlm.nih.gov/pubmed/21522364 http://dx.doi.org/10.1107/S1600536811004442 |
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author | Saraswathi, B. S. Foro, Sabine Gowda, B. Thimme |
author_facet | Saraswathi, B. S. Foro, Sabine Gowda, B. Thimme |
author_sort | Saraswathi, B. S. |
collection | PubMed |
description | In the title compound, C(18)H(20)N(2)O(2), the conformations of the N—H and C=O bonds in the C—NH—C(O)—C segments are anti to each other and the amide O atom is anti to the H atoms attached to the adjacent C atoms. Further, the conformations of the N—H bonds in the amide fragments are anti to the ortho-methyl groups in the adjacent benzene rings. The complete molecule is generated by inversion symmetry. The dihedral angle between the benzene ring and the NH—C(O)—CH(2) segment in the two halves of the molecule is 62.1 (2)°. In the crystal, N—H⋯O intermolecular hydrogen bonds link the molecules into sheet-like infinite chains along the a axis. |
format | Text |
id | pubmed-3052079 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30520792011-04-26 N,N′-Bis(2-methylphenyl)succinamide Saraswathi, B. S. Foro, Sabine Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(20)N(2)O(2), the conformations of the N—H and C=O bonds in the C—NH—C(O)—C segments are anti to each other and the amide O atom is anti to the H atoms attached to the adjacent C atoms. Further, the conformations of the N—H bonds in the amide fragments are anti to the ortho-methyl groups in the adjacent benzene rings. The complete molecule is generated by inversion symmetry. The dihedral angle between the benzene ring and the NH—C(O)—CH(2) segment in the two halves of the molecule is 62.1 (2)°. In the crystal, N—H⋯O intermolecular hydrogen bonds link the molecules into sheet-like infinite chains along the a axis. International Union of Crystallography 2011-02-12 /pmc/articles/PMC3052079/ /pubmed/21522364 http://dx.doi.org/10.1107/S1600536811004442 Text en © Saraswathi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Saraswathi, B. S. Foro, Sabine Gowda, B. Thimme N,N′-Bis(2-methylphenyl)succinamide |
title |
N,N′-Bis(2-methylphenyl)succinamide |
title_full |
N,N′-Bis(2-methylphenyl)succinamide |
title_fullStr |
N,N′-Bis(2-methylphenyl)succinamide |
title_full_unstemmed |
N,N′-Bis(2-methylphenyl)succinamide |
title_short |
N,N′-Bis(2-methylphenyl)succinamide |
title_sort | n,n′-bis(2-methylphenyl)succinamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052079/ https://www.ncbi.nlm.nih.gov/pubmed/21522364 http://dx.doi.org/10.1107/S1600536811004442 |
work_keys_str_mv | AT saraswathibs nnbis2methylphenylsuccinamide AT forosabine nnbis2methylphenylsuccinamide AT gowdabthimme nnbis2methylphenylsuccinamide |