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tert-Butyl N-{(1S)-1-[(2,4-dihy­droxy­benzyl­idene)hydrazinecarbon­yl]-2-hy­droxy­eth­yl}carbamate ethanol monosolvate

The mol­ecule of the title ethanol solvate, C(15)H(21)N(3)O(6)·C(2)H(6)O, adopts a curved shape; the conformation about the imine bond [N=N = 1.287 (3) Å] is E. The amide residues occupy positions almost orthogonal to each other [dihedral angle = 85.7 (2)°]. In the crystal, a network of O—H⋯O, O—H⋯N...

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Autores principales: Pinheiro, Alessandra C., de Souza, Marcus V. N., Tiekink, Edward R. T., Wardell, Solange M. S. V., Wardell, James L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052090/
https://www.ncbi.nlm.nih.gov/pubmed/21522343
http://dx.doi.org/10.1107/S1600536811003795
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author Pinheiro, Alessandra C.
de Souza, Marcus V. N.
Tiekink, Edward R. T.
Wardell, Solange M. S. V.
Wardell, James L.
author_facet Pinheiro, Alessandra C.
de Souza, Marcus V. N.
Tiekink, Edward R. T.
Wardell, Solange M. S. V.
Wardell, James L.
author_sort Pinheiro, Alessandra C.
collection PubMed
description The mol­ecule of the title ethanol solvate, C(15)H(21)N(3)O(6)·C(2)H(6)O, adopts a curved shape; the conformation about the imine bond [N=N = 1.287 (3) Å] is E. The amide residues occupy positions almost orthogonal to each other [dihedral angle = 85.7 (2)°]. In the crystal, a network of O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds leads to the formation of supra­molecular arrays in the ab plane with the ethanol mol­ecules lying to the periphery on either side. Disorder in the solvent ethanol mol­ecule was evident with two positions being resolved for the C atoms [site occupancy of the major component = 0.612 (10)].
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spelling pubmed-30520902011-04-26 tert-Butyl N-{(1S)-1-[(2,4-dihy­droxy­benzyl­idene)hydrazinecarbon­yl]-2-hy­droxy­eth­yl}carbamate ethanol monosolvate Pinheiro, Alessandra C. de Souza, Marcus V. N. Tiekink, Edward R. T. Wardell, Solange M. S. V. Wardell, James L. Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title ethanol solvate, C(15)H(21)N(3)O(6)·C(2)H(6)O, adopts a curved shape; the conformation about the imine bond [N=N = 1.287 (3) Å] is E. The amide residues occupy positions almost orthogonal to each other [dihedral angle = 85.7 (2)°]. In the crystal, a network of O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds leads to the formation of supra­molecular arrays in the ab plane with the ethanol mol­ecules lying to the periphery on either side. Disorder in the solvent ethanol mol­ecule was evident with two positions being resolved for the C atoms [site occupancy of the major component = 0.612 (10)]. International Union of Crystallography 2011-02-09 /pmc/articles/PMC3052090/ /pubmed/21522343 http://dx.doi.org/10.1107/S1600536811003795 Text en © Pinheiro et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pinheiro, Alessandra C.
de Souza, Marcus V. N.
Tiekink, Edward R. T.
Wardell, Solange M. S. V.
Wardell, James L.
tert-Butyl N-{(1S)-1-[(2,4-dihy­droxy­benzyl­idene)hydrazinecarbon­yl]-2-hy­droxy­eth­yl}carbamate ethanol monosolvate
title tert-Butyl N-{(1S)-1-[(2,4-dihy­droxy­benzyl­idene)hydrazinecarbon­yl]-2-hy­droxy­eth­yl}carbamate ethanol monosolvate
title_full tert-Butyl N-{(1S)-1-[(2,4-dihy­droxy­benzyl­idene)hydrazinecarbon­yl]-2-hy­droxy­eth­yl}carbamate ethanol monosolvate
title_fullStr tert-Butyl N-{(1S)-1-[(2,4-dihy­droxy­benzyl­idene)hydrazinecarbon­yl]-2-hy­droxy­eth­yl}carbamate ethanol monosolvate
title_full_unstemmed tert-Butyl N-{(1S)-1-[(2,4-dihy­droxy­benzyl­idene)hydrazinecarbon­yl]-2-hy­droxy­eth­yl}carbamate ethanol monosolvate
title_short tert-Butyl N-{(1S)-1-[(2,4-dihy­droxy­benzyl­idene)hydrazinecarbon­yl]-2-hy­droxy­eth­yl}carbamate ethanol monosolvate
title_sort tert-butyl n-{(1s)-1-[(2,4-dihy­droxy­benzyl­idene)hydrazinecarbon­yl]-2-hy­droxy­eth­yl}carbamate ethanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052090/
https://www.ncbi.nlm.nih.gov/pubmed/21522343
http://dx.doi.org/10.1107/S1600536811003795
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