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tert-Butyl N-{(1S)-1-[(2,4-dihydroxybenzylidene)hydrazinecarbonyl]-2-hydroxyethyl}carbamate ethanol monosolvate
The molecule of the title ethanol solvate, C(15)H(21)N(3)O(6)·C(2)H(6)O, adopts a curved shape; the conformation about the imine bond [N=N = 1.287 (3) Å] is E. The amide residues occupy positions almost orthogonal to each other [dihedral angle = 85.7 (2)°]. In the crystal, a network of O—H⋯O, O—H⋯N...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052090/ https://www.ncbi.nlm.nih.gov/pubmed/21522343 http://dx.doi.org/10.1107/S1600536811003795 |
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author | Pinheiro, Alessandra C. de Souza, Marcus V. N. Tiekink, Edward R. T. Wardell, Solange M. S. V. Wardell, James L. |
author_facet | Pinheiro, Alessandra C. de Souza, Marcus V. N. Tiekink, Edward R. T. Wardell, Solange M. S. V. Wardell, James L. |
author_sort | Pinheiro, Alessandra C. |
collection | PubMed |
description | The molecule of the title ethanol solvate, C(15)H(21)N(3)O(6)·C(2)H(6)O, adopts a curved shape; the conformation about the imine bond [N=N = 1.287 (3) Å] is E. The amide residues occupy positions almost orthogonal to each other [dihedral angle = 85.7 (2)°]. In the crystal, a network of O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds leads to the formation of supramolecular arrays in the ab plane with the ethanol molecules lying to the periphery on either side. Disorder in the solvent ethanol molecule was evident with two positions being resolved for the C atoms [site occupancy of the major component = 0.612 (10)]. |
format | Text |
id | pubmed-3052090 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30520902011-04-26 tert-Butyl N-{(1S)-1-[(2,4-dihydroxybenzylidene)hydrazinecarbonyl]-2-hydroxyethyl}carbamate ethanol monosolvate Pinheiro, Alessandra C. de Souza, Marcus V. N. Tiekink, Edward R. T. Wardell, Solange M. S. V. Wardell, James L. Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title ethanol solvate, C(15)H(21)N(3)O(6)·C(2)H(6)O, adopts a curved shape; the conformation about the imine bond [N=N = 1.287 (3) Å] is E. The amide residues occupy positions almost orthogonal to each other [dihedral angle = 85.7 (2)°]. In the crystal, a network of O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds leads to the formation of supramolecular arrays in the ab plane with the ethanol molecules lying to the periphery on either side. Disorder in the solvent ethanol molecule was evident with two positions being resolved for the C atoms [site occupancy of the major component = 0.612 (10)]. International Union of Crystallography 2011-02-09 /pmc/articles/PMC3052090/ /pubmed/21522343 http://dx.doi.org/10.1107/S1600536811003795 Text en © Pinheiro et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Pinheiro, Alessandra C. de Souza, Marcus V. N. Tiekink, Edward R. T. Wardell, Solange M. S. V. Wardell, James L. tert-Butyl N-{(1S)-1-[(2,4-dihydroxybenzylidene)hydrazinecarbonyl]-2-hydroxyethyl}carbamate ethanol monosolvate |
title |
tert-Butyl N-{(1S)-1-[(2,4-dihydroxybenzylidene)hydrazinecarbonyl]-2-hydroxyethyl}carbamate ethanol monosolvate |
title_full |
tert-Butyl N-{(1S)-1-[(2,4-dihydroxybenzylidene)hydrazinecarbonyl]-2-hydroxyethyl}carbamate ethanol monosolvate |
title_fullStr |
tert-Butyl N-{(1S)-1-[(2,4-dihydroxybenzylidene)hydrazinecarbonyl]-2-hydroxyethyl}carbamate ethanol monosolvate |
title_full_unstemmed |
tert-Butyl N-{(1S)-1-[(2,4-dihydroxybenzylidene)hydrazinecarbonyl]-2-hydroxyethyl}carbamate ethanol monosolvate |
title_short |
tert-Butyl N-{(1S)-1-[(2,4-dihydroxybenzylidene)hydrazinecarbonyl]-2-hydroxyethyl}carbamate ethanol monosolvate |
title_sort | tert-butyl n-{(1s)-1-[(2,4-dihydroxybenzylidene)hydrazinecarbonyl]-2-hydroxyethyl}carbamate ethanol monosolvate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052090/ https://www.ncbi.nlm.nih.gov/pubmed/21522343 http://dx.doi.org/10.1107/S1600536811003795 |
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