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trans-Dichloridobis(propane-1,3-diamine-κ(2) N,N′)chromium(III) perchlorate

In the title compound, [CrCl(2)(C(3)H(10)N(2))(2)]ClO(4), the Cr(III) atom is coordinated equatorially by four N atoms of two propane-1,3-diamine (tn) ligands and axially by two mutually trans Cl atoms, thus displaying a slightly distorted octa­hedral geometry with no crystallographically imposed sy...

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Detalles Bibliográficos
Autores principales: Choi, Jong-Ha, Clegg, William
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052098/
https://www.ncbi.nlm.nih.gov/pubmed/21522301
http://dx.doi.org/10.1107/S1600536811006349
Descripción
Sumario:In the title compound, [CrCl(2)(C(3)H(10)N(2))(2)]ClO(4), the Cr(III) atom is coordinated equatorially by four N atoms of two propane-1,3-diamine (tn) ligands and axially by two mutually trans Cl atoms, thus displaying a slightly distorted octa­hedral geometry with no crystallographically imposed symmetry. The two six-membered chair chelate rings in the complex cation are in an anti conformation with respect to each other. The Cr—N bond lengths range from 2.0831 (18) to 2.0917 (19) Å, and the Cr—Cl bond lengths are 2.3148 (6) and 2.3135 (6) Å. The perchlorate anions have slightly distorted tetra­hedral geometries. Weak inter­molecular hydrogen bonds involving the tn ligand NH groups as donors, and chloride ligands and anion O atoms as acceptors are observed.