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trans-Dichloridobis(propane-1,3-diamine-κ(2) N,N′)chromium(III) perchlorate

In the title compound, [CrCl(2)(C(3)H(10)N(2))(2)]ClO(4), the Cr(III) atom is coordinated equatorially by four N atoms of two propane-1,3-diamine (tn) ligands and axially by two mutually trans Cl atoms, thus displaying a slightly distorted octa­hedral geometry with no crystallographically imposed sy...

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Autores principales: Choi, Jong-Ha, Clegg, William
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052098/
https://www.ncbi.nlm.nih.gov/pubmed/21522301
http://dx.doi.org/10.1107/S1600536811006349
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author Choi, Jong-Ha
Clegg, William
author_facet Choi, Jong-Ha
Clegg, William
author_sort Choi, Jong-Ha
collection PubMed
description In the title compound, [CrCl(2)(C(3)H(10)N(2))(2)]ClO(4), the Cr(III) atom is coordinated equatorially by four N atoms of two propane-1,3-diamine (tn) ligands and axially by two mutually trans Cl atoms, thus displaying a slightly distorted octa­hedral geometry with no crystallographically imposed symmetry. The two six-membered chair chelate rings in the complex cation are in an anti conformation with respect to each other. The Cr—N bond lengths range from 2.0831 (18) to 2.0917 (19) Å, and the Cr—Cl bond lengths are 2.3148 (6) and 2.3135 (6) Å. The perchlorate anions have slightly distorted tetra­hedral geometries. Weak inter­molecular hydrogen bonds involving the tn ligand NH groups as donors, and chloride ligands and anion O atoms as acceptors are observed.
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spelling pubmed-30520982011-04-26 trans-Dichloridobis(propane-1,3-diamine-κ(2) N,N′)chromium(III) perchlorate Choi, Jong-Ha Clegg, William Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CrCl(2)(C(3)H(10)N(2))(2)]ClO(4), the Cr(III) atom is coordinated equatorially by four N atoms of two propane-1,3-diamine (tn) ligands and axially by two mutually trans Cl atoms, thus displaying a slightly distorted octa­hedral geometry with no crystallographically imposed symmetry. The two six-membered chair chelate rings in the complex cation are in an anti conformation with respect to each other. The Cr—N bond lengths range from 2.0831 (18) to 2.0917 (19) Å, and the Cr—Cl bond lengths are 2.3148 (6) and 2.3135 (6) Å. The perchlorate anions have slightly distorted tetra­hedral geometries. Weak inter­molecular hydrogen bonds involving the tn ligand NH groups as donors, and chloride ligands and anion O atoms as acceptors are observed. International Union of Crystallography 2011-02-26 /pmc/articles/PMC3052098/ /pubmed/21522301 http://dx.doi.org/10.1107/S1600536811006349 Text en © Choi and Clegg 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Choi, Jong-Ha
Clegg, William
trans-Dichloridobis(propane-1,3-diamine-κ(2) N,N′)chromium(III) perchlorate
title trans-Dichloridobis(propane-1,3-diamine-κ(2) N,N′)chromium(III) perchlorate
title_full trans-Dichloridobis(propane-1,3-diamine-κ(2) N,N′)chromium(III) perchlorate
title_fullStr trans-Dichloridobis(propane-1,3-diamine-κ(2) N,N′)chromium(III) perchlorate
title_full_unstemmed trans-Dichloridobis(propane-1,3-diamine-κ(2) N,N′)chromium(III) perchlorate
title_short trans-Dichloridobis(propane-1,3-diamine-κ(2) N,N′)chromium(III) perchlorate
title_sort trans-dichloridobis(propane-1,3-diamine-κ(2) n,n′)chromium(iii) perchlorate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052098/
https://www.ncbi.nlm.nih.gov/pubmed/21522301
http://dx.doi.org/10.1107/S1600536811006349
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