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trans-Dichloridobis(propane-1,3-diamine-κ(2) N,N′)chromium(III) perchlorate
In the title compound, [CrCl(2)(C(3)H(10)N(2))(2)]ClO(4), the Cr(III) atom is coordinated equatorially by four N atoms of two propane-1,3-diamine (tn) ligands and axially by two mutually trans Cl atoms, thus displaying a slightly distorted octahedral geometry with no crystallographically imposed sy...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052098/ https://www.ncbi.nlm.nih.gov/pubmed/21522301 http://dx.doi.org/10.1107/S1600536811006349 |
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author | Choi, Jong-Ha Clegg, William |
author_facet | Choi, Jong-Ha Clegg, William |
author_sort | Choi, Jong-Ha |
collection | PubMed |
description | In the title compound, [CrCl(2)(C(3)H(10)N(2))(2)]ClO(4), the Cr(III) atom is coordinated equatorially by four N atoms of two propane-1,3-diamine (tn) ligands and axially by two mutually trans Cl atoms, thus displaying a slightly distorted octahedral geometry with no crystallographically imposed symmetry. The two six-membered chair chelate rings in the complex cation are in an anti conformation with respect to each other. The Cr—N bond lengths range from 2.0831 (18) to 2.0917 (19) Å, and the Cr—Cl bond lengths are 2.3148 (6) and 2.3135 (6) Å. The perchlorate anions have slightly distorted tetrahedral geometries. Weak intermolecular hydrogen bonds involving the tn ligand NH groups as donors, and chloride ligands and anion O atoms as acceptors are observed. |
format | Text |
id | pubmed-3052098 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30520982011-04-26 trans-Dichloridobis(propane-1,3-diamine-κ(2) N,N′)chromium(III) perchlorate Choi, Jong-Ha Clegg, William Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CrCl(2)(C(3)H(10)N(2))(2)]ClO(4), the Cr(III) atom is coordinated equatorially by four N atoms of two propane-1,3-diamine (tn) ligands and axially by two mutually trans Cl atoms, thus displaying a slightly distorted octahedral geometry with no crystallographically imposed symmetry. The two six-membered chair chelate rings in the complex cation are in an anti conformation with respect to each other. The Cr—N bond lengths range from 2.0831 (18) to 2.0917 (19) Å, and the Cr—Cl bond lengths are 2.3148 (6) and 2.3135 (6) Å. The perchlorate anions have slightly distorted tetrahedral geometries. Weak intermolecular hydrogen bonds involving the tn ligand NH groups as donors, and chloride ligands and anion O atoms as acceptors are observed. International Union of Crystallography 2011-02-26 /pmc/articles/PMC3052098/ /pubmed/21522301 http://dx.doi.org/10.1107/S1600536811006349 Text en © Choi and Clegg 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Choi, Jong-Ha Clegg, William trans-Dichloridobis(propane-1,3-diamine-κ(2) N,N′)chromium(III) perchlorate |
title |
trans-Dichloridobis(propane-1,3-diamine-κ(2)
N,N′)chromium(III) perchlorate |
title_full |
trans-Dichloridobis(propane-1,3-diamine-κ(2)
N,N′)chromium(III) perchlorate |
title_fullStr |
trans-Dichloridobis(propane-1,3-diamine-κ(2)
N,N′)chromium(III) perchlorate |
title_full_unstemmed |
trans-Dichloridobis(propane-1,3-diamine-κ(2)
N,N′)chromium(III) perchlorate |
title_short |
trans-Dichloridobis(propane-1,3-diamine-κ(2)
N,N′)chromium(III) perchlorate |
title_sort | trans-dichloridobis(propane-1,3-diamine-κ(2)
n,n′)chromium(iii) perchlorate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052098/ https://www.ncbi.nlm.nih.gov/pubmed/21522301 http://dx.doi.org/10.1107/S1600536811006349 |
work_keys_str_mv | AT choijongha transdichloridobispropane13diaminek2nnchromiumiiiperchlorate AT cleggwilliam transdichloridobispropane13diaminek2nnchromiumiiiperchlorate |