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Dimethyl 8-acetyl-2-methyl-1,2-dihydro­quinoline-2,4-dicarboxyl­ate

In the title compound, C(16)H(17)NO(5), the six-membered N-containing ring has a half-boat form; the spiro C atom deviates by 0.34 (2) Å from the plane (r.m.s. deviation = 0.051 Å) defined by the N and four aromatic C atoms. Intra­molecular N—H⋯O hydrogen bonding generates an S(6) ring motif and the...

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Detalles Bibliográficos
Autores principales: Keleşoğlu, Zeynep, Gültekin, Zeynep, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052105/
https://www.ncbi.nlm.nih.gov/pubmed/21522312
http://dx.doi.org/10.1107/S1600536811003564
Descripción
Sumario:In the title compound, C(16)H(17)NO(5), the six-membered N-containing ring has a half-boat form; the spiro C atom deviates by 0.34 (2) Å from the plane (r.m.s. deviation = 0.051 Å) defined by the N and four aromatic C atoms. Intra­molecular N—H⋯O hydrogen bonding generates an S(6) ring motif and the dihedral angle between the mean plane though the S(6) ring and that through the five-atom half-boat plane is 3.39 (2)°. In the crystal, weak inter­molecular C—H⋯O hydrogen bonds link mol­ecules into zigzag chains along [001] due to c-glide symmetry, and C—H⋯π inter­actions extend along [010].