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Dimethyl 8-acetyl-2-methyl-1,2-dihydro­quinoline-2,4-dicarboxyl­ate

In the title compound, C(16)H(17)NO(5), the six-membered N-containing ring has a half-boat form; the spiro C atom deviates by 0.34 (2) Å from the plane (r.m.s. deviation = 0.051 Å) defined by the N and four aromatic C atoms. Intra­molecular N—H⋯O hydrogen bonding generates an S(6) ring motif and the...

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Autores principales: Keleşoğlu, Zeynep, Gültekin, Zeynep, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052105/
https://www.ncbi.nlm.nih.gov/pubmed/21522312
http://dx.doi.org/10.1107/S1600536811003564
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author Keleşoğlu, Zeynep
Gültekin, Zeynep
Büyükgüngör, Orhan
author_facet Keleşoğlu, Zeynep
Gültekin, Zeynep
Büyükgüngör, Orhan
author_sort Keleşoğlu, Zeynep
collection PubMed
description In the title compound, C(16)H(17)NO(5), the six-membered N-containing ring has a half-boat form; the spiro C atom deviates by 0.34 (2) Å from the plane (r.m.s. deviation = 0.051 Å) defined by the N and four aromatic C atoms. Intra­molecular N—H⋯O hydrogen bonding generates an S(6) ring motif and the dihedral angle between the mean plane though the S(6) ring and that through the five-atom half-boat plane is 3.39 (2)°. In the crystal, weak inter­molecular C—H⋯O hydrogen bonds link mol­ecules into zigzag chains along [001] due to c-glide symmetry, and C—H⋯π inter­actions extend along [010].
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spelling pubmed-30521052011-04-26 Dimethyl 8-acetyl-2-methyl-1,2-dihydro­quinoline-2,4-dicarboxyl­ate Keleşoğlu, Zeynep Gültekin, Zeynep Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(17)NO(5), the six-membered N-containing ring has a half-boat form; the spiro C atom deviates by 0.34 (2) Å from the plane (r.m.s. deviation = 0.051 Å) defined by the N and four aromatic C atoms. Intra­molecular N—H⋯O hydrogen bonding generates an S(6) ring motif and the dihedral angle between the mean plane though the S(6) ring and that through the five-atom half-boat plane is 3.39 (2)°. In the crystal, weak inter­molecular C—H⋯O hydrogen bonds link mol­ecules into zigzag chains along [001] due to c-glide symmetry, and C—H⋯π inter­actions extend along [010]. International Union of Crystallography 2011-02-02 /pmc/articles/PMC3052105/ /pubmed/21522312 http://dx.doi.org/10.1107/S1600536811003564 Text en © Keleşoğlu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Keleşoğlu, Zeynep
Gültekin, Zeynep
Büyükgüngör, Orhan
Dimethyl 8-acetyl-2-methyl-1,2-dihydro­quinoline-2,4-dicarboxyl­ate
title Dimethyl 8-acetyl-2-methyl-1,2-dihydro­quinoline-2,4-dicarboxyl­ate
title_full Dimethyl 8-acetyl-2-methyl-1,2-dihydro­quinoline-2,4-dicarboxyl­ate
title_fullStr Dimethyl 8-acetyl-2-methyl-1,2-dihydro­quinoline-2,4-dicarboxyl­ate
title_full_unstemmed Dimethyl 8-acetyl-2-methyl-1,2-dihydro­quinoline-2,4-dicarboxyl­ate
title_short Dimethyl 8-acetyl-2-methyl-1,2-dihydro­quinoline-2,4-dicarboxyl­ate
title_sort dimethyl 8-acetyl-2-methyl-1,2-dihydro­quinoline-2,4-dicarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052105/
https://www.ncbi.nlm.nih.gov/pubmed/21522312
http://dx.doi.org/10.1107/S1600536811003564
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