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Dimethyl 8-acetyl-2-methyl-1,2-dihydroquinoline-2,4-dicarboxylate
In the title compound, C(16)H(17)NO(5), the six-membered N-containing ring has a half-boat form; the spiro C atom deviates by 0.34 (2) Å from the plane (r.m.s. deviation = 0.051 Å) defined by the N and four aromatic C atoms. Intramolecular N—H⋯O hydrogen bonding generates an S(6) ring motif and the...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052105/ https://www.ncbi.nlm.nih.gov/pubmed/21522312 http://dx.doi.org/10.1107/S1600536811003564 |
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author | Keleşoğlu, Zeynep Gültekin, Zeynep Büyükgüngör, Orhan |
author_facet | Keleşoğlu, Zeynep Gültekin, Zeynep Büyükgüngör, Orhan |
author_sort | Keleşoğlu, Zeynep |
collection | PubMed |
description | In the title compound, C(16)H(17)NO(5), the six-membered N-containing ring has a half-boat form; the spiro C atom deviates by 0.34 (2) Å from the plane (r.m.s. deviation = 0.051 Å) defined by the N and four aromatic C atoms. Intramolecular N—H⋯O hydrogen bonding generates an S(6) ring motif and the dihedral angle between the mean plane though the S(6) ring and that through the five-atom half-boat plane is 3.39 (2)°. In the crystal, weak intermolecular C—H⋯O hydrogen bonds link molecules into zigzag chains along [001] due to c-glide symmetry, and C—H⋯π interactions extend along [010]. |
format | Text |
id | pubmed-3052105 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30521052011-04-26 Dimethyl 8-acetyl-2-methyl-1,2-dihydroquinoline-2,4-dicarboxylate Keleşoğlu, Zeynep Gültekin, Zeynep Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(17)NO(5), the six-membered N-containing ring has a half-boat form; the spiro C atom deviates by 0.34 (2) Å from the plane (r.m.s. deviation = 0.051 Å) defined by the N and four aromatic C atoms. Intramolecular N—H⋯O hydrogen bonding generates an S(6) ring motif and the dihedral angle between the mean plane though the S(6) ring and that through the five-atom half-boat plane is 3.39 (2)°. In the crystal, weak intermolecular C—H⋯O hydrogen bonds link molecules into zigzag chains along [001] due to c-glide symmetry, and C—H⋯π interactions extend along [010]. International Union of Crystallography 2011-02-02 /pmc/articles/PMC3052105/ /pubmed/21522312 http://dx.doi.org/10.1107/S1600536811003564 Text en © Keleşoğlu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Keleşoğlu, Zeynep Gültekin, Zeynep Büyükgüngör, Orhan Dimethyl 8-acetyl-2-methyl-1,2-dihydroquinoline-2,4-dicarboxylate |
title | Dimethyl 8-acetyl-2-methyl-1,2-dihydroquinoline-2,4-dicarboxylate |
title_full | Dimethyl 8-acetyl-2-methyl-1,2-dihydroquinoline-2,4-dicarboxylate |
title_fullStr | Dimethyl 8-acetyl-2-methyl-1,2-dihydroquinoline-2,4-dicarboxylate |
title_full_unstemmed | Dimethyl 8-acetyl-2-methyl-1,2-dihydroquinoline-2,4-dicarboxylate |
title_short | Dimethyl 8-acetyl-2-methyl-1,2-dihydroquinoline-2,4-dicarboxylate |
title_sort | dimethyl 8-acetyl-2-methyl-1,2-dihydroquinoline-2,4-dicarboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052105/ https://www.ncbi.nlm.nih.gov/pubmed/21522312 http://dx.doi.org/10.1107/S1600536811003564 |
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