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Azido{4,4′-dibromo-2,2′-[ethane-1,2-diyl­bis(nitrilo­methanylylidene)]diphenol­ato-κ(4) O,N,N′,O′}manganese(III)

In the title compound, [Mn(C(16)H(12)Br(2)N(2)O(2))(N(3))], the Mn(III) ion is chelated by a tetra­dentate Schiff base ligand and coordinated by the N atom of an azide ligand in a distorted square-pyramidal arrangement. It forms phenolate-bridged out-of-plane dimers with Mn⋯O(phenolate) distances of...

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Detalles Bibliográficos
Autor principal: Liu, Yingxia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052106/
https://www.ncbi.nlm.nih.gov/pubmed/21522254
http://dx.doi.org/10.1107/S1600536811004594
Descripción
Sumario:In the title compound, [Mn(C(16)H(12)Br(2)N(2)O(2))(N(3))], the Mn(III) ion is chelated by a tetra­dentate Schiff base ligand and coordinated by the N atom of an azide ligand in a distorted square-pyramidal arrangement. It forms phenolate-bridged out-of-plane dimers with Mn⋯O(phenolate) distances of 2.667 (2) Å between pairs of inversion-related mol­ecules. In the crystal, there are offset inter-complex face-to-face π–π inter­actions [centroid–centroid distances = 3.598 (2) Å] involving one of the benzene rings of the ligands.