Azido{4,4′-dibromo-2,2′-[ethane-1,2-diyl­bis(nitrilo­methanylylidene)]diphenol­ato-κ(4) O,N,N′,O′}manganese(III)

In the title compound, [Mn(C(16)H(12)Br(2)N(2)O(2))(N(3))], the Mn(III) ion is chelated by a tetra­dentate Schiff base ligand and coordinated by the N atom of an azide ligand in a distorted square-pyramidal arrangement. It forms phenolate-bridged out-of-plane dimers with Mn⋯O(phenolate) distances of...

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Autor principal: Liu, Yingxia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052106/
https://www.ncbi.nlm.nih.gov/pubmed/21522254
http://dx.doi.org/10.1107/S1600536811004594
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author Liu, Yingxia
author_facet Liu, Yingxia
author_sort Liu, Yingxia
collection PubMed
description In the title compound, [Mn(C(16)H(12)Br(2)N(2)O(2))(N(3))], the Mn(III) ion is chelated by a tetra­dentate Schiff base ligand and coordinated by the N atom of an azide ligand in a distorted square-pyramidal arrangement. It forms phenolate-bridged out-of-plane dimers with Mn⋯O(phenolate) distances of 2.667 (2) Å between pairs of inversion-related mol­ecules. In the crystal, there are offset inter-complex face-to-face π–π inter­actions [centroid–centroid distances = 3.598 (2) Å] involving one of the benzene rings of the ligands.
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spelling pubmed-30521062011-04-26 Azido{4,4′-dibromo-2,2′-[ethane-1,2-diyl­bis(nitrilo­methanylylidene)]diphenol­ato-κ(4) O,N,N′,O′}manganese(III) Liu, Yingxia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(16)H(12)Br(2)N(2)O(2))(N(3))], the Mn(III) ion is chelated by a tetra­dentate Schiff base ligand and coordinated by the N atom of an azide ligand in a distorted square-pyramidal arrangement. It forms phenolate-bridged out-of-plane dimers with Mn⋯O(phenolate) distances of 2.667 (2) Å between pairs of inversion-related mol­ecules. In the crystal, there are offset inter-complex face-to-face π–π inter­actions [centroid–centroid distances = 3.598 (2) Å] involving one of the benzene rings of the ligands. International Union of Crystallography 2011-02-12 /pmc/articles/PMC3052106/ /pubmed/21522254 http://dx.doi.org/10.1107/S1600536811004594 Text en © Yingxia Liu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Yingxia
Azido{4,4′-dibromo-2,2′-[ethane-1,2-diyl­bis(nitrilo­methanylylidene)]diphenol­ato-κ(4) O,N,N′,O′}manganese(III)
title Azido{4,4′-dibromo-2,2′-[ethane-1,2-diyl­bis(nitrilo­methanylylidene)]diphenol­ato-κ(4) O,N,N′,O′}manganese(III)
title_full Azido{4,4′-dibromo-2,2′-[ethane-1,2-diyl­bis(nitrilo­methanylylidene)]diphenol­ato-κ(4) O,N,N′,O′}manganese(III)
title_fullStr Azido{4,4′-dibromo-2,2′-[ethane-1,2-diyl­bis(nitrilo­methanylylidene)]diphenol­ato-κ(4) O,N,N′,O′}manganese(III)
title_full_unstemmed Azido{4,4′-dibromo-2,2′-[ethane-1,2-diyl­bis(nitrilo­methanylylidene)]diphenol­ato-κ(4) O,N,N′,O′}manganese(III)
title_short Azido{4,4′-dibromo-2,2′-[ethane-1,2-diyl­bis(nitrilo­methanylylidene)]diphenol­ato-κ(4) O,N,N′,O′}manganese(III)
title_sort azido{4,4′-dibromo-2,2′-[ethane-1,2-diyl­bis(nitrilo­methanylylidene)]diphenol­ato-κ(4) o,n,n′,o′}manganese(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052106/
https://www.ncbi.nlm.nih.gov/pubmed/21522254
http://dx.doi.org/10.1107/S1600536811004594
work_keys_str_mv AT liuyingxia azido44dibromo22ethane12diylbisnitrilomethanylylidenediphenolatok4onnomanganeseiii

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