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Azido{4,4′-dibromo-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ(4) O,N,N′,O′}manganese(III)
In the title compound, [Mn(C(16)H(12)Br(2)N(2)O(2))(N(3))], the Mn(III) ion is chelated by a tetradentate Schiff base ligand and coordinated by the N atom of an azide ligand in a distorted square-pyramidal arrangement. It forms phenolate-bridged out-of-plane dimers with Mn⋯O(phenolate) distances of...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052106/ https://www.ncbi.nlm.nih.gov/pubmed/21522254 http://dx.doi.org/10.1107/S1600536811004594 |