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(1S,3R,8R)-9-(1-Amino­ethyl­idene)-2,2-dichloro-3,7,7-trimethyl­tricyclo­[6.4.0.0(1,3)]undecan-10-one

The title compound, C(16)H(23)Cl(2)NO, was synthesised from β-himachalene (3,5,5,9-tetra­methyl-2,4a,5,6,7,8-hexa­hydro-1H-benzocyclo­heptene), which was isolated from the essential oil of the Atlas cedar (Cedrus Atlantica). The mol­ecule contains a seven membered ring, which is fused to a five- and...

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Detalles Bibliográficos
Autores principales: Benharref, Ahmed, Lassaba, Essêdiya, Avignant, Daniel, Oudahmane, Abdelghani, Berraho, Moha
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052109/
https://www.ncbi.nlm.nih.gov/pubmed/21522398
http://dx.doi.org/10.1107/S1600536811005307
Descripción
Sumario:The title compound, C(16)H(23)Cl(2)NO, was synthesised from β-himachalene (3,5,5,9-tetra­methyl-2,4a,5,6,7,8-hexa­hydro-1H-benzocyclo­heptene), which was isolated from the essential oil of the Atlas cedar (Cedrus Atlantica). The mol­ecule contains a seven membered ring, which is fused to a five- and a three-membered ring. The five-membered ring has a twisted conformation, whereas the seven-membered ring displays a chair conformation. The dihedral angle between the five- and seven-membered rings is 45.26 (9)°. The absolute structure was established unambiguously from anomalous dispersion effects. In the crystal, mol­ecules are linked into chains propagating along the b axis by inter­molecular N—H⋯O hydrogen bonds; an intramolecular N—H⋯O link also occurs.