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2-[1-(3-{2-[(2-Hy­droxy­benzyl­idene)amino]­phen­oxy}prop­yl)-1H-1,3-benzodiazol-2-yl]phenol

In the title compound, C(29)H(25)N(3)O(3), the imine double bond has an E configuration. The dihedral angle between the hy­droxy­phenyl and benzene rings in the imine moiety is 26.95 (9)°, and the dihedral angle between the hy­droxy­phenyl and benzimidazole rings in the other moiety is 14.83 (9)°. T...

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Autores principales: Keypour, Hassan, Tamizi, Sareh, Dehghanpour, Saeed, Azadbakht, Reza, Khalaj, Mehdi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052110/
https://www.ncbi.nlm.nih.gov/pubmed/21522409
http://dx.doi.org/10.1107/S1600536811005319
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author Keypour, Hassan
Tamizi, Sareh
Dehghanpour, Saeed
Azadbakht, Reza
Khalaj, Mehdi
author_facet Keypour, Hassan
Tamizi, Sareh
Dehghanpour, Saeed
Azadbakht, Reza
Khalaj, Mehdi
author_sort Keypour, Hassan
collection PubMed
description In the title compound, C(29)H(25)N(3)O(3), the imine double bond has an E configuration. The dihedral angle between the hy­droxy­phenyl and benzene rings in the imine moiety is 26.95 (9)°, and the dihedral angle between the hy­droxy­phenyl and benzimidazole rings in the other moiety is 14.83 (9)°. These angles are probably limited to small values as a consequence of two strong intra­molecular O—H⋯N hydrogen bonds formed between the hy­droxy groups and the imine and imidazole N atoms. The aliphatic chain linking the two ring systems has a gauche conformation, as reflected in C—C—C—O torsion angle of 70.9 (2)°.
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spelling pubmed-30521102011-04-26 2-[1-(3-{2-[(2-Hy­droxy­benzyl­idene)amino]­phen­oxy}prop­yl)-1H-1,3-benzodiazol-2-yl]phenol Keypour, Hassan Tamizi, Sareh Dehghanpour, Saeed Azadbakht, Reza Khalaj, Mehdi Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(29)H(25)N(3)O(3), the imine double bond has an E configuration. The dihedral angle between the hy­droxy­phenyl and benzene rings in the imine moiety is 26.95 (9)°, and the dihedral angle between the hy­droxy­phenyl and benzimidazole rings in the other moiety is 14.83 (9)°. These angles are probably limited to small values as a consequence of two strong intra­molecular O—H⋯N hydrogen bonds formed between the hy­droxy groups and the imine and imidazole N atoms. The aliphatic chain linking the two ring systems has a gauche conformation, as reflected in C—C—C—O torsion angle of 70.9 (2)°. International Union of Crystallography 2011-02-19 /pmc/articles/PMC3052110/ /pubmed/21522409 http://dx.doi.org/10.1107/S1600536811005319 Text en © Keypour et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Keypour, Hassan
Tamizi, Sareh
Dehghanpour, Saeed
Azadbakht, Reza
Khalaj, Mehdi
2-[1-(3-{2-[(2-Hy­droxy­benzyl­idene)amino]­phen­oxy}prop­yl)-1H-1,3-benzodiazol-2-yl]phenol
title 2-[1-(3-{2-[(2-Hy­droxy­benzyl­idene)amino]­phen­oxy}prop­yl)-1H-1,3-benzodiazol-2-yl]phenol
title_full 2-[1-(3-{2-[(2-Hy­droxy­benzyl­idene)amino]­phen­oxy}prop­yl)-1H-1,3-benzodiazol-2-yl]phenol
title_fullStr 2-[1-(3-{2-[(2-Hy­droxy­benzyl­idene)amino]­phen­oxy}prop­yl)-1H-1,3-benzodiazol-2-yl]phenol
title_full_unstemmed 2-[1-(3-{2-[(2-Hy­droxy­benzyl­idene)amino]­phen­oxy}prop­yl)-1H-1,3-benzodiazol-2-yl]phenol
title_short 2-[1-(3-{2-[(2-Hy­droxy­benzyl­idene)amino]­phen­oxy}prop­yl)-1H-1,3-benzodiazol-2-yl]phenol
title_sort 2-[1-(3-{2-[(2-hy­droxy­benzyl­idene)amino]­phen­oxy}prop­yl)-1h-1,3-benzodiazol-2-yl]phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052110/
https://www.ncbi.nlm.nih.gov/pubmed/21522409
http://dx.doi.org/10.1107/S1600536811005319
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