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2,4-Bis[(3-butylimidazol-3-ium-1-yl)methyl]-1,3,5-trimethylbenzene bis(hexafluorophosphate)
In the title molecular salt, C(25)H(38)N(4) (2+)·2PF(6) (−), one of the butyl groups and four F atoms in the basal plane of one of the PF(6) (−) octahedra are disordered over two sets of sites, with occupancy ratios of 0.704 (5):0.296 (5) and 0.71 (3):0.29 (3), respectively. The central benzene rin...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052114/ https://www.ncbi.nlm.nih.gov/pubmed/21522326 http://dx.doi.org/10.1107/S1600536811003916 |
| Sumario: | In the title molecular salt, C(25)H(38)N(4) (2+)·2PF(6) (−), one of the butyl groups and four F atoms in the basal plane of one of the PF(6) (−) octahedra are disordered over two sets of sites, with occupancy ratios of 0.704 (5):0.296 (5) and 0.71 (3):0.29 (3), respectively. The central benzene ring makes dihedral angles of 85.17 (12) and 81.97 (12)° with the terminal imidazole rings. In the crystal, cations and anions are linked together via intermolecular C—H⋯F hydrogen bonds forming a three-dimensional network. |
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