2,4-Bis[(3-butyl­imidazol-3-ium-1-yl)meth­yl]-1,3,5-trimethyl­benzene bis­(hexa­fluoro­phosphate)

In the title molecular salt, C(25)H(38)N(4) (2+)·2PF(6) (−), one of the butyl groups and four F atoms in the basal plane of one of the PF(6) (−) octa­hedra are disordered over two sets of sites, with occupancy ratios of 0.704 (5):0.296 (5) and 0.71 (3):0.29 (3), respectively. The central benzene rin...

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Autores principales: Haque, Rosenani A., Salman, Abbas Washeel, Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052114/
https://www.ncbi.nlm.nih.gov/pubmed/21522326
http://dx.doi.org/10.1107/S1600536811003916
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author Haque, Rosenani A.
Salman, Abbas Washeel
Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Haque, Rosenani A.
Salman, Abbas Washeel
Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Haque, Rosenani A.
collection PubMed
description In the title molecular salt, C(25)H(38)N(4) (2+)·2PF(6) (−), one of the butyl groups and four F atoms in the basal plane of one of the PF(6) (−) octa­hedra are disordered over two sets of sites, with occupancy ratios of 0.704 (5):0.296 (5) and 0.71 (3):0.29 (3), respectively. The central benzene ring makes dihedral angles of 85.17 (12) and 81.97 (12)° with the terminal imidazole rings. In the crystal, cations and anions are linked together via inter­molecular C—H⋯F hydrogen bonds forming a three-dimensional network.
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spelling pubmed-30521142011-04-26 2,4-Bis[(3-butyl­imidazol-3-ium-1-yl)meth­yl]-1,3,5-trimethyl­benzene bis­(hexa­fluoro­phosphate) Haque, Rosenani A. Salman, Abbas Washeel Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecular salt, C(25)H(38)N(4) (2+)·2PF(6) (−), one of the butyl groups and four F atoms in the basal plane of one of the PF(6) (−) octa­hedra are disordered over two sets of sites, with occupancy ratios of 0.704 (5):0.296 (5) and 0.71 (3):0.29 (3), respectively. The central benzene ring makes dihedral angles of 85.17 (12) and 81.97 (12)° with the terminal imidazole rings. In the crystal, cations and anions are linked together via inter­molecular C—H⋯F hydrogen bonds forming a three-dimensional network. International Union of Crystallography 2011-02-05 /pmc/articles/PMC3052114/ /pubmed/21522326 http://dx.doi.org/10.1107/S1600536811003916 Text en © Haque et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Haque, Rosenani A.
Salman, Abbas Washeel
Hemamalini, Madhukar
Fun, Hoong-Kun
2,4-Bis[(3-butyl­imidazol-3-ium-1-yl)meth­yl]-1,3,5-trimethyl­benzene bis­(hexa­fluoro­phosphate)
title 2,4-Bis[(3-butyl­imidazol-3-ium-1-yl)meth­yl]-1,3,5-trimethyl­benzene bis­(hexa­fluoro­phosphate)
title_full 2,4-Bis[(3-butyl­imidazol-3-ium-1-yl)meth­yl]-1,3,5-trimethyl­benzene bis­(hexa­fluoro­phosphate)
title_fullStr 2,4-Bis[(3-butyl­imidazol-3-ium-1-yl)meth­yl]-1,3,5-trimethyl­benzene bis­(hexa­fluoro­phosphate)
title_full_unstemmed 2,4-Bis[(3-butyl­imidazol-3-ium-1-yl)meth­yl]-1,3,5-trimethyl­benzene bis­(hexa­fluoro­phosphate)
title_short 2,4-Bis[(3-butyl­imidazol-3-ium-1-yl)meth­yl]-1,3,5-trimethyl­benzene bis­(hexa­fluoro­phosphate)
title_sort 2,4-bis[(3-butyl­imidazol-3-ium-1-yl)meth­yl]-1,3,5-trimethyl­benzene bis­(hexa­fluoro­phosphate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052114/
https://www.ncbi.nlm.nih.gov/pubmed/21522326
http://dx.doi.org/10.1107/S1600536811003916
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