4-Bromo-3-methyl­anilinium perchlorate 18-crown-6 clathrate

The reaction of 4-bromo-3-methyl­anilinium perchlorate and 18-crown-6 in methanol solution yielded the title compound, C(7)H(9)BrN(+)·ClO(4) (−)·C(12)H(24)O(6). The protonated 4-bromo-3-methyl­amine unit contains one –NH(3) (+) substituent, resulting in a 1:1 supra­molecular rotator–stator structure...

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Detalles Bibliográficos
Autores principales: Xu, Qian, Zhao, Min Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052115/
https://www.ncbi.nlm.nih.gov/pubmed/21522341
http://dx.doi.org/10.1107/S1600536811003540
Descripción
Sumario:The reaction of 4-bromo-3-methyl­anilinium perchlorate and 18-crown-6 in methanol solution yielded the title compound, C(7)H(9)BrN(+)·ClO(4) (−)·C(12)H(24)O(6). The protonated 4-bromo-3-methyl­amine unit contains one –NH(3) (+) substituent, resulting in a 1:1 supra­molecular rotator–stator structure, (C(7)H(9)Br—NH(3) (+))(18-crown-6), through three bifurcated N—H⋯(O,O) hydrogen bonds between the ammonium group of the cation and the O atoms of the crown ether mol­ecule.

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