4-Bromo-3-methyl­anilinium perchlorate 18-crown-6 clathrate

The reaction of 4-bromo-3-methyl­anilinium perchlorate and 18-crown-6 in methanol solution yielded the title compound, C(7)H(9)BrN(+)·ClO(4) (−)·C(12)H(24)O(6). The protonated 4-bromo-3-methyl­amine unit contains one –NH(3) (+) substituent, resulting in a 1:1 supra­molecular rotator–stator structure...

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Detalles Bibliográficos
Autores principales: Xu, Qian, Zhao, Min Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052115/
https://www.ncbi.nlm.nih.gov/pubmed/21522341
http://dx.doi.org/10.1107/S1600536811003540
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author Xu, Qian
Zhao, Min Min
author_facet Xu, Qian
Zhao, Min Min
author_sort Xu, Qian
collection PubMed
description The reaction of 4-bromo-3-methyl­anilinium perchlorate and 18-crown-6 in methanol solution yielded the title compound, C(7)H(9)BrN(+)·ClO(4) (−)·C(12)H(24)O(6). The protonated 4-bromo-3-methyl­amine unit contains one –NH(3) (+) substituent, resulting in a 1:1 supra­molecular rotator–stator structure, (C(7)H(9)Br—NH(3) (+))(18-crown-6), through three bifurcated N—H⋯(O,O) hydrogen bonds between the ammonium group of the cation and the O atoms of the crown ether mol­ecule.
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spelling pubmed-30521152011-04-26 4-Bromo-3-methyl­anilinium perchlorate 18-crown-6 clathrate Xu, Qian Zhao, Min Min Acta Crystallogr Sect E Struct Rep Online Organic Papers The reaction of 4-bromo-3-methyl­anilinium perchlorate and 18-crown-6 in methanol solution yielded the title compound, C(7)H(9)BrN(+)·ClO(4) (−)·C(12)H(24)O(6). The protonated 4-bromo-3-methyl­amine unit contains one –NH(3) (+) substituent, resulting in a 1:1 supra­molecular rotator–stator structure, (C(7)H(9)Br—NH(3) (+))(18-crown-6), through three bifurcated N—H⋯(O,O) hydrogen bonds between the ammonium group of the cation and the O atoms of the crown ether mol­ecule. International Union of Crystallography 2011-02-05 /pmc/articles/PMC3052115/ /pubmed/21522341 http://dx.doi.org/10.1107/S1600536811003540 Text en © Xu and Zhao 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Xu, Qian
Zhao, Min Min
4-Bromo-3-methyl­anilinium perchlorate 18-crown-6 clathrate
title 4-Bromo-3-methyl­anilinium perchlorate 18-crown-6 clathrate
title_full 4-Bromo-3-methyl­anilinium perchlorate 18-crown-6 clathrate
title_fullStr 4-Bromo-3-methyl­anilinium perchlorate 18-crown-6 clathrate
title_full_unstemmed 4-Bromo-3-methyl­anilinium perchlorate 18-crown-6 clathrate
title_short 4-Bromo-3-methyl­anilinium perchlorate 18-crown-6 clathrate
title_sort 4-bromo-3-methyl­anilinium perchlorate 18-crown-6 clathrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052115/
https://www.ncbi.nlm.nih.gov/pubmed/21522341
http://dx.doi.org/10.1107/S1600536811003540
work_keys_str_mv AT xuqian 4bromo3methylaniliniumperchlorate18crown6clathrate
AT zhaominmin 4bromo3methylaniliniumperchlorate18crown6clathrate

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