Ethyl 5-bromo-1-benzofuran-2-carboxyl­ate

In the title compound, C(11)H(9)BrO(3), the benzofuran fused-ring system is almost planar, with a maximum atomic deviation of 0.024 (5) Å; the carboxyl –CO(2) fragment is aligned at 4.8 (7)° with respect to the fused-ring plane. Weak inter­molecular C—H⋯O hydrogen bonding is present in the crystal s...

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Detalles Bibliográficos
Autores principales: Abdel-Aziz, Hatem A., Bari, Ahmed, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052120/
https://www.ncbi.nlm.nih.gov/pubmed/21522441
http://dx.doi.org/10.1107/S1600536811005897
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author Abdel-Aziz, Hatem A.
Bari, Ahmed
Ng, Seik Weng
author_facet Abdel-Aziz, Hatem A.
Bari, Ahmed
Ng, Seik Weng
author_sort Abdel-Aziz, Hatem A.
collection PubMed
description In the title compound, C(11)H(9)BrO(3), the benzofuran fused-ring system is almost planar, with a maximum atomic deviation of 0.024 (5) Å; the carboxyl –CO(2) fragment is aligned at 4.8 (7)° with respect to the fused-ring plane. Weak inter­molecular C—H⋯O hydrogen bonding is present in the crystal structure. π–π stacking is also observed between parallel mol­ecules, the centroid–centroid distance between benzene and furan rings of adjacent mol­ecules being 3.662 (3) Å.
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spelling pubmed-30521202011-04-26 Ethyl 5-bromo-1-benzofuran-2-carboxyl­ate Abdel-Aziz, Hatem A. Bari, Ahmed Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(9)BrO(3), the benzofuran fused-ring system is almost planar, with a maximum atomic deviation of 0.024 (5) Å; the carboxyl –CO(2) fragment is aligned at 4.8 (7)° with respect to the fused-ring plane. Weak inter­molecular C—H⋯O hydrogen bonding is present in the crystal structure. π–π stacking is also observed between parallel mol­ecules, the centroid–centroid distance between benzene and furan rings of adjacent mol­ecules being 3.662 (3) Å. International Union of Crystallography 2011-02-23 /pmc/articles/PMC3052120/ /pubmed/21522441 http://dx.doi.org/10.1107/S1600536811005897 Text en © Abdel-Aziz et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Abdel-Aziz, Hatem A.
Bari, Ahmed
Ng, Seik Weng
Ethyl 5-bromo-1-benzofuran-2-carboxyl­ate
title Ethyl 5-bromo-1-benzofuran-2-carboxyl­ate
title_full Ethyl 5-bromo-1-benzofuran-2-carboxyl­ate
title_fullStr Ethyl 5-bromo-1-benzofuran-2-carboxyl­ate
title_full_unstemmed Ethyl 5-bromo-1-benzofuran-2-carboxyl­ate
title_short Ethyl 5-bromo-1-benzofuran-2-carboxyl­ate
title_sort ethyl 5-bromo-1-benzofuran-2-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052120/
https://www.ncbi.nlm.nih.gov/pubmed/21522441
http://dx.doi.org/10.1107/S1600536811005897
work_keys_str_mv AT abdelazizhatema ethyl5bromo1benzofuran2carboxylate
AT bariahmed ethyl5bromo1benzofuran2carboxylate
AT ngseikweng ethyl5bromo1benzofuran2carboxylate

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