(2,2′-Bipyridyl-κ(2) N,N′)bis­(N-butyl-N-methyl­dithio­carbamato-κ(2) S,S′)cadmium(II)

The Cd(II) atom in the title compound, [Cd(C(6)H(12)NS(2))(2)(C(10)H(8)N(2))], is hexa­coordinated by two dithio­carbamate ligands and the N atoms from a bidentate 2,2′-bipyridyl mol­ecule. The coordination geometry is based on a distorted trigonal–prismatic arrangement of the N(2)S(4) donor set. Su...

Descripción completa

Detalles Bibliográficos
Autores principales: Jamaluddin, Nur Amirah, Baba, Ibrahim, Mohamed Tahir, Mohamed Ibrahim, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052129/
https://www.ncbi.nlm.nih.gov/pubmed/21522303
http://dx.doi.org/10.1107/S1600536811006878
_version_ 1782199634367610880
author Jamaluddin, Nur Amirah
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
author_facet Jamaluddin, Nur Amirah
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
author_sort Jamaluddin, Nur Amirah
collection PubMed
description The Cd(II) atom in the title compound, [Cd(C(6)H(12)NS(2))(2)(C(10)H(8)N(2))], is hexa­coordinated by two dithio­carbamate ligands and the N atoms from a bidentate 2,2′-bipyridyl mol­ecule. The coordination geometry is based on a distorted trigonal–prismatic arrangement of the N(2)S(4) donor set. Supra­molecular chains, aligned along the a-axis direction, are mediated by C—H⋯S inter­actions and these are connected into layers that stack along the c axis via π–π inter­actions [Cg(pyrid­yl)⋯Cg(pyrid­yl) = 3.6587 (13) Å].
format Text
id pubmed-3052129
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30521292011-04-26 (2,2′-Bipyridyl-κ(2) N,N′)bis­(N-butyl-N-methyl­dithio­carbamato-κ(2) S,S′)cadmium(II) Jamaluddin, Nur Amirah Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cd(II) atom in the title compound, [Cd(C(6)H(12)NS(2))(2)(C(10)H(8)N(2))], is hexa­coordinated by two dithio­carbamate ligands and the N atoms from a bidentate 2,2′-bipyridyl mol­ecule. The coordination geometry is based on a distorted trigonal–prismatic arrangement of the N(2)S(4) donor set. Supra­molecular chains, aligned along the a-axis direction, are mediated by C—H⋯S inter­actions and these are connected into layers that stack along the c axis via π–π inter­actions [Cg(pyrid­yl)⋯Cg(pyrid­yl) = 3.6587 (13) Å]. International Union of Crystallography 2011-02-26 /pmc/articles/PMC3052129/ /pubmed/21522303 http://dx.doi.org/10.1107/S1600536811006878 Text en © Jamaluddin et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jamaluddin, Nur Amirah
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
(2,2′-Bipyridyl-κ(2) N,N′)bis­(N-butyl-N-methyl­dithio­carbamato-κ(2) S,S′)cadmium(II)
title (2,2′-Bipyridyl-κ(2) N,N′)bis­(N-butyl-N-methyl­dithio­carbamato-κ(2) S,S′)cadmium(II)
title_full (2,2′-Bipyridyl-κ(2) N,N′)bis­(N-butyl-N-methyl­dithio­carbamato-κ(2) S,S′)cadmium(II)
title_fullStr (2,2′-Bipyridyl-κ(2) N,N′)bis­(N-butyl-N-methyl­dithio­carbamato-κ(2) S,S′)cadmium(II)
title_full_unstemmed (2,2′-Bipyridyl-κ(2) N,N′)bis­(N-butyl-N-methyl­dithio­carbamato-κ(2) S,S′)cadmium(II)
title_short (2,2′-Bipyridyl-κ(2) N,N′)bis­(N-butyl-N-methyl­dithio­carbamato-κ(2) S,S′)cadmium(II)
title_sort (2,2′-bipyridyl-κ(2) n,n′)bis­(n-butyl-n-methyl­dithio­carbamato-κ(2) s,s′)cadmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052129/
https://www.ncbi.nlm.nih.gov/pubmed/21522303
http://dx.doi.org/10.1107/S1600536811006878
work_keys_str_mv AT jamaluddinnuramirah 22bipyridylk2nnbisnbutylnmethyldithiocarbamatok2sscadmiumii
AT babaibrahim 22bipyridylk2nnbisnbutylnmethyldithiocarbamatok2sscadmiumii
AT mohamedtahirmohamedibrahim 22bipyridylk2nnbisnbutylnmethyldithiocarbamatok2sscadmiumii
AT tiekinkedwardrt 22bipyridylk2nnbisnbutylnmethyldithiocarbamatok2sscadmiumii