(2,2′-Bipyridyl-κ(2) N,N′)bis(N-butyl-N-methyldithiocarbamato-κ(2) S,S′)cadmium(II)
The Cd(II) atom in the title compound, [Cd(C(6)H(12)NS(2))(2)(C(10)H(8)N(2))], is hexacoordinated by two dithiocarbamate ligands and the N atoms from a bidentate 2,2′-bipyridyl molecule. The coordination geometry is based on a distorted trigonal–prismatic arrangement of the N(2)S(4) donor set. Su...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052129/ https://www.ncbi.nlm.nih.gov/pubmed/21522303 http://dx.doi.org/10.1107/S1600536811006878 |
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author | Jamaluddin, Nur Amirah Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. |
author_facet | Jamaluddin, Nur Amirah Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. |
author_sort | Jamaluddin, Nur Amirah |
collection | PubMed |
description | The Cd(II) atom in the title compound, [Cd(C(6)H(12)NS(2))(2)(C(10)H(8)N(2))], is hexacoordinated by two dithiocarbamate ligands and the N atoms from a bidentate 2,2′-bipyridyl molecule. The coordination geometry is based on a distorted trigonal–prismatic arrangement of the N(2)S(4) donor set. Supramolecular chains, aligned along the a-axis direction, are mediated by C—H⋯S interactions and these are connected into layers that stack along the c axis via π–π interactions [Cg(pyridyl)⋯Cg(pyridyl) = 3.6587 (13) Å]. |
format | Text |
id | pubmed-3052129 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30521292011-04-26 (2,2′-Bipyridyl-κ(2) N,N′)bis(N-butyl-N-methyldithiocarbamato-κ(2) S,S′)cadmium(II) Jamaluddin, Nur Amirah Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cd(II) atom in the title compound, [Cd(C(6)H(12)NS(2))(2)(C(10)H(8)N(2))], is hexacoordinated by two dithiocarbamate ligands and the N atoms from a bidentate 2,2′-bipyridyl molecule. The coordination geometry is based on a distorted trigonal–prismatic arrangement of the N(2)S(4) donor set. Supramolecular chains, aligned along the a-axis direction, are mediated by C—H⋯S interactions and these are connected into layers that stack along the c axis via π–π interactions [Cg(pyridyl)⋯Cg(pyridyl) = 3.6587 (13) Å]. International Union of Crystallography 2011-02-26 /pmc/articles/PMC3052129/ /pubmed/21522303 http://dx.doi.org/10.1107/S1600536811006878 Text en © Jamaluddin et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Jamaluddin, Nur Amirah Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. (2,2′-Bipyridyl-κ(2) N,N′)bis(N-butyl-N-methyldithiocarbamato-κ(2) S,S′)cadmium(II) |
title | (2,2′-Bipyridyl-κ(2)
N,N′)bis(N-butyl-N-methyldithiocarbamato-κ(2)
S,S′)cadmium(II) |
title_full | (2,2′-Bipyridyl-κ(2)
N,N′)bis(N-butyl-N-methyldithiocarbamato-κ(2)
S,S′)cadmium(II) |
title_fullStr | (2,2′-Bipyridyl-κ(2)
N,N′)bis(N-butyl-N-methyldithiocarbamato-κ(2)
S,S′)cadmium(II) |
title_full_unstemmed | (2,2′-Bipyridyl-κ(2)
N,N′)bis(N-butyl-N-methyldithiocarbamato-κ(2)
S,S′)cadmium(II) |
title_short | (2,2′-Bipyridyl-κ(2)
N,N′)bis(N-butyl-N-methyldithiocarbamato-κ(2)
S,S′)cadmium(II) |
title_sort | (2,2′-bipyridyl-κ(2)
n,n′)bis(n-butyl-n-methyldithiocarbamato-κ(2)
s,s′)cadmium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052129/ https://www.ncbi.nlm.nih.gov/pubmed/21522303 http://dx.doi.org/10.1107/S1600536811006878 |
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