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Poly[diaqua­tris­(μ(4)-1,3-phenyl­enediacetato)­dineodymium(III)]

In the title coordination polymer, [Nd(2)(C(10)H(8)O(4))(3)(H(2)O)(2)](n), each of the two Nd(III) ions is nine-coordinated by eight O atoms from six different 2,2′-(m-phenyl­ene)diacetate (pda) bivalent anions and by one O atom from a water mol­ecule, forming a distorted tricapped trigonal–prismati...

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Detalles Bibliográficos
Autores principales: Gao, Zhu-Qing, Lv, Dong-Yu, Li, Hong-Ji, Gu, Jin-Zhong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052131/
https://www.ncbi.nlm.nih.gov/pubmed/21522305
http://dx.doi.org/10.1107/S1600536811006817
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author Gao, Zhu-Qing
Lv, Dong-Yu
Li, Hong-Ji
Gu, Jin-Zhong
author_facet Gao, Zhu-Qing
Lv, Dong-Yu
Li, Hong-Ji
Gu, Jin-Zhong
author_sort Gao, Zhu-Qing
collection PubMed
description In the title coordination polymer, [Nd(2)(C(10)H(8)O(4))(3)(H(2)O)(2)](n), each of the two Nd(III) ions is nine-coordinated by eight O atoms from six different 2,2′-(m-phenyl­ene)diacetate (pda) bivalent anions and by one O atom from a water mol­ecule, forming a distorted tricapped trigonal–prismatic coordination geometry. Eight Nd(III) ions and 12 pda ligands form a large [Nd(8)(pda)(12)] ring, and four Nd(III) ions and six pda ligands form a small [Nd(4)(pda)(6)] ring. These rings are further connected by the coordination inter­actions of pda ligands and Nd(III), generating a three-dimensional supra­molecular framework.
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spelling pubmed-30521312011-04-26 Poly[diaqua­tris­(μ(4)-1,3-phenyl­enediacetato)­dineodymium(III)] Gao, Zhu-Qing Lv, Dong-Yu Li, Hong-Ji Gu, Jin-Zhong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Nd(2)(C(10)H(8)O(4))(3)(H(2)O)(2)](n), each of the two Nd(III) ions is nine-coordinated by eight O atoms from six different 2,2′-(m-phenyl­ene)diacetate (pda) bivalent anions and by one O atom from a water mol­ecule, forming a distorted tricapped trigonal–prismatic coordination geometry. Eight Nd(III) ions and 12 pda ligands form a large [Nd(8)(pda)(12)] ring, and four Nd(III) ions and six pda ligands form a small [Nd(4)(pda)(6)] ring. These rings are further connected by the coordination inter­actions of pda ligands and Nd(III), generating a three-dimensional supra­molecular framework. International Union of Crystallography 2011-02-26 /pmc/articles/PMC3052131/ /pubmed/21522305 http://dx.doi.org/10.1107/S1600536811006817 Text en © Gao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Zhu-Qing
Lv, Dong-Yu
Li, Hong-Ji
Gu, Jin-Zhong
Poly[diaqua­tris­(μ(4)-1,3-phenyl­enediacetato)­dineodymium(III)]
title Poly[diaqua­tris­(μ(4)-1,3-phenyl­enediacetato)­dineodymium(III)]
title_full Poly[diaqua­tris­(μ(4)-1,3-phenyl­enediacetato)­dineodymium(III)]
title_fullStr Poly[diaqua­tris­(μ(4)-1,3-phenyl­enediacetato)­dineodymium(III)]
title_full_unstemmed Poly[diaqua­tris­(μ(4)-1,3-phenyl­enediacetato)­dineodymium(III)]
title_short Poly[diaqua­tris­(μ(4)-1,3-phenyl­enediacetato)­dineodymium(III)]
title_sort poly[diaqua­tris­(μ(4)-1,3-phenyl­enediacetato)­dineodymium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052131/
https://www.ncbi.nlm.nih.gov/pubmed/21522305
http://dx.doi.org/10.1107/S1600536811006817
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