Dinitro­sylbis[tris­(4-methyl­phen­yl)phosphane]iron

The title compound, [Fe(NO)(2)(C(21)H(21)P)(2)], belongs to the family of metal dinitrosyl compounds with the general formula Fe(NO)(2)(L)(x), referred to collectively as ‘dinitrosyl iron compounds’ (DNICs). Herein we report the structure of a dinitrosyl iron diphosphane complex, [Fe(NO)(2) L (2)],...

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Detalles Bibliográficos
Autores principales: Jones, Myron W., Powell, Douglas R., Richter-Addo, George B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3052133/
https://www.ncbi.nlm.nih.gov/pubmed/21522262
http://dx.doi.org/10.1107/S160053681100465X
Descripción
Sumario:The title compound, [Fe(NO)(2)(C(21)H(21)P)(2)], belongs to the family of metal dinitrosyl compounds with the general formula Fe(NO)(2)(L)(x), referred to collectively as ‘dinitrosyl iron compounds’ (DNICs). Herein we report the structure of a dinitrosyl iron diphosphane complex, [Fe(NO)(2) L (2)], with L = P(C(6)H(4)-p-CH(3))(3). There are two crystallographically independent but chemically equal mol­ecules per asymmetric unit. The iron atom in each mol­ecule is tetra­hedrally coordinated by two phosphane ligands and two NO groups, with Fe—N—O angles in the range 173.84 (15)–179.31 (16)°.

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